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Organic Printed Core-Shell Heterostructure Arrays: A Universal Approach to All-Color Laser Display Panels
摘要： We demonstrate a universal approach for realizing dual-wavelength lasing in organic core-shell structured microlaser arrays, which show great promise in serving as all-color laser display panels. By alternately printing hydrophilic and hydrophobic laser dye solutions on preprocessed substrates, we successfully obtained precisely patterned core-shell heterostructure arrays. The spatially-separated core and shell independently function as optical resonators to support dual-wavelength tunable microlasers in each heterostructure. Such a general method enables to flexibly control the lasing wavelength of the core-shell microlasers across a wide spectral range by systematically designing the gain media. Using as-prepared microlaser arrays as display panels, we achieved full-color laser displays, representing an achievable color gamut much larger than that of standard RGB space. These results may provide new insights for design concepts and device construction for novel optoelectronic applications.
关键词： laser display,organic heterostructure,core-shell structure,dual-wavelength laser,laser array
更新于2025-09-23 15:19:57
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Developing Lattice Matched ZnMgSe Shells on InZnP Quantum Dots for Phosphor Applications
摘要： Indium phosphide quantum dots (QDs) have drawn attention as alternatives to cadmium and lead based QDs that are currently used as phosphors in lamps and displays. The main drawbacks of InP QDs are, in general, a lower photoluminescence quantum yield (PLQY), a decreased color purity and poor chemical stability. In this research, we attempted to increase the PLQY and stability of indium phosphide QDs by developing lattice matched InP/MgSe core-shell nano-heterostructures. The choice of MgSe comes from the fact that, in theory, it has a near-perfect lattice match with InP, provided MgSe is grown in the zinc blende crystal structure, which can be achieved by alloying with zinc. To retain lattice matching we used Zn in both the core and the shell and we fabricated InZnP/ZnxMg1-xSe core/shell QDs. To identify the most suitable conditions for shell growth, we first developed a synthesis route to ZnxMg1-xSe nanocrystals (NCs) wherein Mg is effectively incorporated. Our optimized procedure was employed for the successful growth of ZnxMg1-xSe shells around In(Zn)P QDs. The corresponding core/shell systems exhibit PLQYs higher than those of the starting In(Zn)P QDs and, more importantly, a higher color purity upon increasing the Mg content. The results are discussed in the context of a reduced density of interface states upon using better lattice matched ZnxMg1-xSe shells.
关键词： MgSe,Quantum Dots,lattice matching,core-shell,InP,phosphor
更新于2025-09-23 15:19:57
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Plasmonic Enhancement of Dye Fluorescence in Polymer/Metal Nanocomposites
摘要： The effect of the plasmonic enhancement of dye fluorescence in poly(vinyl butyral) films containing Ag/SiO2 core-shell nanoparticles has been thoroughly studied. It has been shown that the magnitude of this effect can be quite large (up to 5 times) even for a dye having a very high quantum yield (coumarin 7). Therewith, it substantially depends on the size and concentration of Ag/SiO2 particles and the quantum yield of a dye. The results obtained are discussed with involvement of mechanisms reported in the literature for plasmonic enhancement of fluorescence of dyes characterized by high and low quantum yields.
关键词： plasmonic enhancement,dye fluorescence,quantum yield,polymer/metal nanocomposites,Ag/SiO2 core-shell nanoparticles
更新于2025-09-23 15:19:57
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Sandwich magnetically imprinted immunosensor for electrochemiluminescence ultrasensing diethylstilbestrol based on enhanced luminescence of Ru@SiO2 by CdTe@ZnS quantum dots
摘要： A molecularly imprinted magnetic sensor with electroluminescent tags (MIP-ECL sensor) was developed for ultrasensing diethylstilbestrol (DES). A strategy is exploited to enhance ECL emission of the [Ru(bpy)3]2 +-tripropyl amine (TPrA) system by CdTe@ZnS quantum-dots (QDs) through energy transfer. Magnetically molecularly imprinted nanoparticles (MMIPs NPs) based on Fe3O4@SiO2 carriers are artificial, easily reproducible, and could replace easily inactivated first antibodies for capturing more DES molecules. Functionalized bio-conjugates of single antibody-CdTe@ZnS (Ab-CdTe@ZnS) are for the first time loaded on signal labels of Ru(bpy)3 2 +-doped silica nanocomposites (Ru@SiO2) for signal amplification. The final bio-conjugated signal probes are denoted as Ab-DES/CdTe@ZnS-Ru@SiO2. MMIPs beads that have captured antigens are bio-conjugated with antibody-labeled luminescent probes by specific immunoreactive reaction, and then the luminescent immunocomplex generates ECL signal on the magnetic electrode. The logarithm of ECL intensities depend linearly on the logarithm of DES concentrations in the range from 4.8×10? 4 to 36.0 nM with a detection limit of 0.025 pM. This novel assay is much more sensitive than other MIP sensors, and achieves lower cost and more enhanced stability than other immunosensors. The sensor is significantly potential and has been applied to DES detection in actual environment.
关键词： [Ru(bpy)3]2+-doped silica,Probe-mode ECL sensor,Core-shell QDs,Magnetically imprinted nanoparticles,Diethylstilbestrol,Single antibody sandwich-type
更新于2025-09-23 15:19:57
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Impact of dielectric environment on the linear and nonlinear optical properties for CdS/ZnS cylindrical core/shell quantum dots
摘要： By the mean of the effective mass approximation (E.M.A) and compact density matrix method, the energy eigenvalues, linear and nonlinear dielectric function have been theoretically investigated for CdS/ZnS cylindrical core/shell quantum dot embedded in PVA, PMMA and SiO2 matrices. Simulation results showed that the presence of the dielectric mismatch in the QD-matrix system can lead to a significant enhancement of the nonlinear dielectric function. According to our calculations, peaks of the real and imaginary part of the dielectric function can experience a redshift or a blue shift with the appropriate dielectric environment.
关键词： complex dielectric function,Effective mass approximation,cylindrical core/shell quantum dot,density matrix approach
更新于2025-09-23 15:19:57
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Efficient and Stable CdSe/CdS/ZnS Quantum Rods-in-Matrix Assembly for White LED Application
摘要： CdSe/CdS core-shell quantum rods (QRs) are a promising prospect in optoelectronic applications but usually have a relatively low quantum efficiency and stability. Here, we report on an efficient and stable CdSe/CdS/ZnS QRs-in-matrix assembly (QRAs) by growing and embedding CdSe/CdS QRs in ZnS matrices. Structural characterizations show that the CdSe/CdS QRs are encapsulated and interconnected by ZnS in the QRAs structure. The stable ZnS encapsulation renders the CdSe/CdS QRs high quantum efficiency (QE) up to 85%. The QRAs also present high photo- and thermal-stability and can preserve 93% of the initial QE at 100°C. The QRAs powder presents a light degradation of only 2% under continuous excitation for 100 h, displaying profound potential in optoelectronic applications. White light-emitting diodes (WLEDs) are fabricated by packaging the QRAs powder as phosphor on top of blue GaN chip. The WLED shows high optical performance and light quality.
关键词： stability,assembly,light-emitting diodes,quantum rod,core-shell
更新于2025-09-23 15:19:57
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Plasmonic Electronsa??Driven Solara??toa??Hydrocarbon Conversion over Au NR@ZnO Corea??Shell Nanostructures
摘要： This work demonstrates the long-range redox reactivity of gold plasmon-generated hot electrons for solar-driven CO2 conversion. A series of Au NR@ZnO core-shell photocatalysts with a tunable shell thickness are rationally designed to achieve the solar-to-CH4 conversion, where the hot plasmonic electrons-induced photoreduction takes place on the polar oxide moiety. The shell thickness-independent activity implies that the core, gold nanorods, plays a dominant role in the CH4 generation. The ZnO metal oxide semiconductor shell is beneficial to prolong the lifetime of hot electrons, thereby enhancing the photocatalytic efficiency. However, the thickness of ZnO shell is not relevant to the production rate. Both of these two parts are co-excitated by solar light and synergetic enhance the photocatalytic activity.
关键词： gold nanorod,core-shell nanostructure,ZnO,photocatalysis,CO2 photoreduction,plasmon resonance
更新于2025-09-23 15:19:57
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Plasmonic responses of Cua??Ag bimetallic system: Influence of distinctiveness and arrangements
摘要： In this article, the effect of the distinctiveness and arrangements on the plasmonic resonance of Cu–Ag system were studied by finite element method, and the effect of morphologies on the plasmonic properties of Cu@Ag core@shell NPs and Cu–Ag corn-cob liked NPs was investigated by experiment. For Cu@Ag core-shell structure, as the fixed thickness of Ag-shell at 10 nm, the dipole plasmon resonance gradually blue-shifts with increasing the radius of Cu core, and as the fixed radius of Cu-core at 50 nm, the feature peak shows a red-shift and broadening with increasing the thickness of Ag shell. For Cu–Ag corn-cob structure, the feature for different Ag coverage are similar to each other and most of the them follow the blue-shifted tendency with the increase the degree of Ag-coverage. Furthermore, as the regular-shaped structure increases (form trigonal to spherical), the plasmon resonance gradually blue shifts, and finally, we use two parameters to describe the different idealized Cu–Ag structure: separation, exterior contact, intersection and core@shell. The combined information from our simulation and experiment will give guidelines for choosing adequate particles when aiming at certain plasmonic properties.
关键词： Finite element method,Structure-property,Core-shell,Cu–Ag corn-cob-liked,Plasmonic absorption
更新于2025-09-23 15:19:57
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Plasmonically driven photocatalytic hydrogen evolution activity of a Pt-functionalized Au@CeO <sub/>2</sub> corea??shell catalyst under visible light
摘要： A ternary hybrid photocatalyst consisting of Au@CeO2 core–shell nanostructures coated with ultralow Pt-functionalized surface contents (Au@CeO2–Pt) was synthesized using a facile hydrothermal method. The Pt-decorated Au@CeO2 core–shell photocatalyst had a large Brunauer–Emmett–Teller (BET) surface area (86.50 m2 g?1) with an abundance of catalytically active sites. The hydrogen production rate over Au@CeO2–Pt under visible light (8.7 mmol mg?1 h?1) was much higher than that observed over binary Au@CeO2 (3.9 mmol mg?1 h?1) and pure CeO2 (0.9 mmol mg?1 h?1) catalysts. Enhancement of the hydrogen evolution reaction (HER) was attributed mainly to the surface plasmon resonance (SPR) effect of the Au cores, which was highly advantageous for light absorption and conversion. In addition, the Pt co-catalyst served as an electron sink that accepted photogenerated electrons migrating from the Au@CeO2 core–shells. This extended the lifetime of the photogenerated charge carriers and resulted in HER activity that was superior to that of the Pt-free photocatalysts. The large BET surface area of the ternary core–shell nanostructure and the presence of many catalytically active sites also enhanced the HER performance.
关键词： photocatalyst,hydrogen evolution,plasmonic,visible light,core–shell
更新于2025-09-23 15:19:57
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Hierarchical Core-Shell Structure of 2D VS2@VC@N-Doped Carbon Sheets Decorated by Ultrafine Pd Nanoparticles: Assembled in 3D Rosette-like Array on Carbon Fiber Microelectrode for Electrochemical Sensing
摘要： The development of two-dimension (2D) nanohybrid materials with heterogeneous component in nanoscale and three-dimension (3D) well-ordered assembly in microscale has been regarded as an effective way to improve their overall performances by synergistic coupling of the optimized structure and composition. In this work, we reported the design and synthesis of a new type of hierarchically core-shell structure of 2D VS2@VC@N-doped carbon (NC) sheets decorated by ultrafine Pd nanoparticles (PdNPs), which were vertically grown on carbon fiber (CF) and assembled into a unique 3D rosette-like array. The resultant VS2@VC@NC-PdNPs modified CF microelectrode integrated the structural and electrochemical properties of the heterogeneous hybridization of core-shell VS2@VC@NC-PdNPs sheets with unique rosette-like array structure, and gave rise to a significant improvement in terms of electron transfer ability, electrocatalytic activity, stability and biocompatibility. Under the optimized conditions, the VS2@VC@NC-PdNPs modified CF microelectrode demonstrated excellent electrochemical sensing performance towards biomarker hydrogen peroxide (H2O2) including high sensitivity of 152.7 μA cm-2 mM-1, low detection limit of 50 nM (a signal-to-noise ratio of 3:1), as well as good reproducibility and anti-interference ability, which could be used for real-time in situ electrochemical detection of H2O2 in live cancer cells and cancer tissue. The remarkable performances of the proposed nanohybrid microelectrode will have a profound impact on the design of diverse 2D layered materials as promising candidate for electrochemical biosensing applications.
关键词： electrochemical sensing,hierarchical core-shell structure,three-dimension rosette-like sheets array,Two-dimension layered nanomaterials,cancer biomarker detection
更新于2025-09-23 15:19:57