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Dielectric tunable properties of Ba0.5Sr0.5TiO3?Mg2TiO4?MgO composite ceramics prepared by spark plasma sintering
摘要： Ba0.5Sr0.5TiO3?Mg2TiO4?MgO composite ceramics were prepared by spark plasma sintering (SPS) technique and their phase composition, microstructures and dielectric tunable properties were studied. With increasing Mg2TiO4?MgO content, the dielectric peaks of Ba0.5Sr0.5TiO3?Mg2TiO4?MgO composite ceramics were broadened and suppressed. The tunability of Ba0.5Sr0.5TiO3?Mg2TiO4?MgO composite ceramics first increased and then decreased with the increase of Mg2TiO4?MgO content. For Mg2TiO4?MgO content ≤ 50 wt%, Ba0.5Sr0.5TiO3?Mg2TiO4?MgO composite ceramics showed higher tunability and lower permittivity than pure Ba0.5Sr0.5TiO3, which can be attributed to the suppression of the doping effect by SPS. The contradiction between reduced permittivity and enhanced tunability in ferroelectric-dielectric composites was resolved.
关键词： Dielectrics,Ferroelectric ceramics,Spark plasma sintering,Composites
更新于2025-11-14 17:28:48
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Thermal properties and remnant state variables of ferroelectric ceramics switched by both electric field and compressive stress at room temperature
摘要： A commercial poled ferroelectric cube specimen is subject to electric ?eld and compressive stress of various magnitudes at the reference temperature 20 °C. After reaching speci?c states of remnant polarization and remnant strains, temperature of the specimen increases under no external load, measuring changes in polarization and strains. Assuming constant values of thermal properties in the temperature range of interest, we estimated pyroelectric and thermal expansion coe?cients for all tested levels of electric and stress ?elds and plotted them versus remnant state variables at 20, 50, 80, and 110 °C. The distributions of thermal properties ?t well into quadratic curves independent of electric and stress ?elds at each of the four temperatures. One could predict successfully the quadratic ?tting curves at high temperatures by using the equations of quadratic ?tting curves at reference temperature. Remnant state variables also seem to have close correlation among themselves, independent of the levels of applied electric ?eld or stress. ? 2018 The Japan Society of Applied Physics
关键词： thermal properties,compressive stress,electric ?eld,ferroelectric ceramics,remnant state variables
更新于2025-09-23 15:21:01
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Coupled phase‐field modeling of domain and fracture evolution in anisotropic ferroelectric ceramics
摘要： The contribution presents a material model for the simulation of domain and fracture evolution in ferroelectric ceramics. Ferroelectric domains and cracks are modeled by using a phase field. While for the modeling of the ferroelectric domains we consider the vectorial electric polarization as order parameter, the modeling of cracks is based on a scalar damage variable. In the present contribution, we discuss the evolution of domains and cracks in an anisotropic ferroelectric solid.
关键词： domain evolution,ferroelectric ceramics,fracture evolution,phase-field modeling,anisotropy
更新于2025-09-16 10:30:52
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Análise da expans?o térmica volumétrica e das características estruturais de solu??es sólidas de (Pb, Ca)TiO3 entre 150 e 570 K
摘要： Ceramic samples of lead modified calcium titanate (Pb1-xCaxTiO3) with calcium concentration between 0.24≤x≤0.55 were prepared and analyzed in order to determine the structural origin of the negative thermal expansion observed in this ferroelectric system. The Rietveld structural refinement method was used to assess the thermal evolution of the structural parameters using powder X-ray diffraction data collected between 150 and 570 K. Since the Pb1-xCaxTiO3 phase diagram and space groups are still unknown for the temperature range investigated, the structural analyses were based on adjustments of the refinement protocol. The results revealed the existence of a correlation between symmetry transitions and anomalies in the thermal expansion of the unit cell, being such transitions not necessarily of the ferroelectric-paraelectric nature.
关键词： Rietveld refinement method,symmetry transitions,structural analyses,unit cell thermal expansion,ferroelectric ceramics
更新于2025-09-04 15:30:14