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Multipole Radiations from Large Gold Nanospheres Excited by Evanescent Wave
摘要： We proposed the use of the evanescent wave generated in a total internal reflection configuration to excite large gold nanospheres and investigated the radiations of the high-order plasmon modes supported in gold nanospheres. It was revealed that the evanescent wave excitation is equivalent to the excitation by using both the incident and reflected light, offering us the opportunity to control the orientation of the electric field used to excite nanoparticles. In addition, it was found that the scattering light intensity is greatly enhanced and the background noise is considerably suppressed, making it possible to detect the radiations from high-order plasmon modes. Moreover, the influence of the mirror images on the scattering induced by a metal substrate is eliminated as compared with the surface plasmon polariton excitation. By exciting a gold nanosphere with s-polarized light and detecting the scattering light with a p-polarized analyzer, we were able to reveal the radiation from the electric quadrupole mode of the gold nanosphere in both the spatial and the frequency domains. Our findings are important for characterizing the radiations from the high-order modes of large nanoparticles and useful for designing nanoscale photonic devices.
关键词： scattering,plasmon mode,electric dipole,radiation pattern,gold nanosphere,evanescent wave,electric octupole,electric quadrupole
更新于2025-11-21 11:24:58
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DNA Enabled Chiral Gold Nanoparticle - Chromophore Hybrid Structure with Resonant Plasmon – Exciton Coupling Gives Unusual and Strong Circular Dichroism
摘要： Circular dichroism (CD) from hybrid complexes of plasmonic nanostructures and chiral molecules has recently attracted significant interest. However, the hierarchical chiral self-assembly of molecules on surfaces of metal nanostructures has remained challenging. As a result, a deep understanding of plasmon-exciton coupling between surface plasmons and chiral collective molecular excitations has not been achieved. In particular, the critical impact of resonant plasmon-exciton coupling within the hybrid is unclear. Here, we employed DNA-templated strategies to control the chiral self-assembly of achiral chromophores with rationally tuned exciton transitions on gold nanosphere (AuNP) or gold nanorod (AuNR) surfaces. Unlike many previous chiral plasmonic hybrids utilizing chiral biomolecules with CD signals in the UV range, we designed structure with the chiral excitonic resonances at visible wavelengths. The constructed hybrid complexes displayed strong chiroptical activity that depends on the spectral overlap between the chiral collective molecular excitations and the plasmon resonances. We find that when spectral overlap is optimized, the molecular CD signal originating from the chiral self-assemblies of chromophores was strongly enhanced (maximum enhancement of nearly an order of magnitude) and a plasmonic CD signal was induced. Surprisingly, the sign of the molecular CD was reversed despite different self-assembly mechanisms of the Au nanoparticle-chromophore hybrids. Our results provide new insight into plasmonic CD enhancements and will inspire further studies on chiral light-matter interactions in strongly coupled plasmonic-excitonic systems.
关键词： DNA-templated strategies,gold nanorod,chiral molecules,chiroptical activity,gold nanosphere,Circular dichroism,plasmonic nanostructures
更新于2025-09-12 10:27:22