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Enhanced heat capacity of binary nitrate eutectic salt-silica nanofluid for solar energy storage
摘要: In concentrating solar power plants, the heat capacity of thermal storage media is a key factor that affects the cost of electricity generation. This work investigated the effective specific heat capacity of binary nitrate eutectic salts seeded with silica nanoparticles, using both experimental measurements and molecular dynamics simulations. The effects of the mass concentration (0–2.0 wt%) and average size (10, 20, and 30 nm) of the nanoparticles on the specific heat capacity value of nanofluids were analyzed. The results show that specific heat capacity increases when adding 10 nm silica nanoparticles up to 1.0 wt%, and then it decreases at higher concentrations. At this optimal mass concentration, the 20 nm nanoparticles displayed a maximum enhancement in the average specific heat capacity (by ~26.7%). The simulation results provided information about the different energy components in the system. The rate of potential energy change versus nanoparticle mass concentration was found to be maximized at 1.0 wt% concentration, which agrees with the experimental measurements. The potential energy components in the simulation system indicate that the change of Coulombic energy contributes the most to the variation of specific heat capacity.
关键词: Molten salt based nanofluids,Molecular dynamics simulation,Solar energy storage,Specific heat capacity
更新于2025-09-23 15:19:57
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Thermal properties of high purity zinc-tellurite glasses for fiber-optics
摘要: The thermal properties of the series glasses (TeO2)(0.86-x)(ZnO)x(La2O3)0.04(Na2O)0.1 were studied. The heat capacity and characteristics of transitions between aggregative states were determined by the method of differential scanning calorimetry (DSC) in the temperature range 320-950 K. The experimentally obtained values of thermal conductivity, density and coefficient of thermal expansion at room temperature are as follows: 1.14 ± 0.06 W/(m?K), 5.20 ± 0.02 g/cm3 and (54.6 ± 1.2)?10-6 K-1, respectively. The model-statistical processing of calorimetric data was used to determine the complete set of standard thermodynamic functions together with their approximation to the unexplored low-temperature region by means of parametric similarity. The approach allows predicting the functions for unexplored intermediate glasses compositions.
关键词: heat capacity,thermal conductivity,thermodynamic functions,coefficient of thermal expansion,density,Zinc-tellurite glasses
更新于2025-09-19 17:15:36
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Broadband terahertz radiation from metal targets irradiated by a short pulse laser
摘要: The generation of low-frequency radiation from sub-picosecond laser pulses incident on metal targets is investigated. The laser field drives time-varying currents in a thin sub-surface layer of the metal, which emits broadband radiation that peaks at terahertz frequencies. We present a one-dimensional electrostatic model for copper appropriate for the interaction of laser pulses at normal incidence combined with a radiation model for an infinitely thin disk. The latter uses as input a single parameter, the temporal dependence of the integrated current density on axis, which is derived from the electrostatic model. The salient characteristics of the emitted radiation, such as power, energy, and spectra, are calculated for laser pulses with various intensities and pulse durations. The radiated energy per unit solid angle peaks at a small angle off the target normal and tapers off at larger angles. Analytical scaling of radiated energy with incident laser energy, in the low frequency limit, is obtained in the form erad ∝ e3/2 laser. For accurate results, it is imperative to use the full expression for the heat capacity of electrons, in both the degenerate and ideal gas limits. Failure to do so may result in inaccuracies for the computed radiated energy, as large as one order of magnitude. A comparison of calculated and measured radiation energy in the 8–12 GHz frequency range indicates a similar trend with laser energy and comparable magnitude (≈1 fJ).
关键词: current density,terahertz radiation,laser-metal interactions,electron heat capacity,broadband radiation
更新于2025-09-19 17:13:59
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Optical Electronics (An Introduction) || 3. Bulk solid-state lasers
摘要: Solid-state lasers use solid-state laser medium as the working substance. Usually, solid work materials are incorporated in the matrix with a small amount of activated ions. Laser transition occurs between different energy levels during ion activation. Matrix materials are mainly crystal, glass, and ceramics, and activated ions can be categorized as trivalent rare earth metal ions, divalent rare earth metal ions, transition metal ions, and actinide metal ions.
关键词: crystal,activated ions,laser medium,heat capacity laser,ceramics,LD-pumped,glass,solid-state lasers
更新于2025-09-16 10:30:52