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Metal ion induced single-crystal-to-single-crystal transformation and luminescent sensing properties of resorcin arene-based metal-organic frameworks
摘要： In this work, two new resorcin[4]arene-based metal-organic frameworks (MOFs), namely, [(CH3)2NH2][Zn3(HL)(L)(DMF)(H2O)2]·2H2O (1-Zn) and [(CH3)2NH2]2[Cd3(L)2(H2O)4]·2DMF·2H2O (2-Cd), have been synthesized under solvothermal conditions (H4L represents the resorcin[4]arene-based ligand). 1-Zn exhibits a layer structure, while 2-Cd shows a 3D motif. Remarkably, by immersing 1-Zn in an aqueous solution of Cu2+ ions, a new Cu(II)-MOF [Cu2(H2L)2(H2O)2]·3.5H2O (1-Cu) was achieved via a metal ion induced single-crystal-to-single-crystal (SCSC) transformation manner, involving generation of new metal-O bond and change of metal ion coordination geometry. Moreover, luminescent detection properties for Fe3+ ions and Cr2O7 2- ions were also investigated with 1-Zn and 2-Cd as luminescent sensors.
关键词： Resorcin[4]arene,Metal-exchanged phrase transformation,Metal-organic framework,Luminescent sensors
更新于2025-09-23 15:23:52
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A Multiport Converter Interfacing Solar Photovoltaic Modules and Energy Storage with DC Microgrid
摘要： A novel real-time optical fibre X-Ray dosimeter for monitoring the radiation pulses delivered from a clinical linear accelerator (Linac) is presented. The primary focus of the sensor is to measure low doses of ionising X-ray radiation in real time (limited to 0.1-ms gate time of the detector). The sensor tip material scintillates upon exposure to X-ray energy and the resultant low-level visible light signal is coupled to a polymethyl methacrylate plastic optical fibre, which is used to guide it towards a distal avalanche photodiode-based detector. The detector measures the low-level scintillating light from the sensor, thereby converting the ionizing radiation energy to a measurable signal with a time resolution of 0.1 ms. Results show that the scintillating optical fibre X-ray dosimeter is capable of capturing the individual X-Ray pulses delivered by the Linac during normal operation. Further examination of the results demonstrates that the sensor is capable of measuring dose rate and, hence, dose with a linearity (R2 = 0.9995 ? 0.9999) and in a highly repeatable manner for dose rates in the range 100 to 600 monitor units/min.
关键词： optical fibre sensors,X-ray dosimetry,Clinical external beam radiotherapy,fluorescent and luminescent sensors,real time radiation dose measurement
更新于2025-09-23 15:21:01
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Combined temperature and radiation effects on radiation sensitive single-mode optical fibers
摘要： A novel real-time optical fibre X-Ray dosimeter for monitoring the radiation pulses delivered from a clinical linear accelerator (Linac) is presented. The primary focus of the sensor is to measure low doses of ionising X-ray radiation in real time (limited to 0.1-ms gate time of the detector). The sensor tip material scintillates upon exposure to X-ray energy and the resultant low-level visible light signal is coupled to a polymethyl methacrylate plastic optical fibre, which is used to guide it towards a distal avalanche photodiode-based detector. The detector measures the low-level scintillating light from the sensor, thereby converting the ionizing radiation energy to a measurable signal with a time resolution of 0.1 ms. Results show that the scintillating optical fibre X-ray dosimeter is capable of capturing the individual X-Ray pulses delivered by the Linac during normal operation. Further examination of the results demonstrates that the sensor is capable of measuring dose rate and, hence, dose with a linearity (R2 = 0.9995 ? 0.9999) and in a highly repeatable manner for dose rates in the range 100 to 600 monitor units/min.
关键词： optical fibre sensors,X-ray dosimetry,Clinical external beam radiotherapy,fluorescent and luminescent sensors,real time radiation dose measurement
更新于2025-09-23 15:21:01
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Synthesis of eight isostructural 2D lanthanide coordination polymers assembled by rigid furan-2,5-dicarboxylic acid and flexible adipic acid as linkers and exploration of luminescent Eu/Tb polymers as efficient and sensitive sensors for nitroaromatic compounds
摘要： Detection of hazardous chemicals is crucial for a healthy and safe environment as well as for the well-being of humans. A confluence of chemistry and engineering continues to improve the sensitivity and selectivity for several classes of harmful chemicals with the promise of cheap and portable sensing. Herein, following the function-oriented research strategy, eight novel lanthanide coordination polymers (Ln-CPs) have been successfully assembled with the framework composition [Ln(2,5-FDC)0.5(Adip)(H2O)2] (Ln = Nd (1), Sm (2), Eu (3), Gd (4), Tb (5), Dy (6), Ho (7), Er (8), 2,5-FDC2? = furan-2,5-dicarboxylate, Adip2? = Adipate) under solvothermal synthesis conditions. The structural analysis indicates that all the eight CPs have the same structural features. All compounds crystallize in the orthorhombic crystal system (space group Pnma) with point symbol {33·44·53} and consist of 2D cem topological type. The linkers 2,5-FDC2? and Adip2? exhibit μ2-κ4,Z1:Z1:Z1:Z1 and μ3-κ5,Z2:Z1:Z1:Z1 coordination modes respectively. The as-synthesized polymers were characterized by powder X-ray crystallography, infrared spectroscopy, thermogravimetric analysis, and photoluminescence studies. CP-3 and CP-5 are promising luminescent lanthanide coordination polymers (Ln-CPs) and function as efficient sensors for the detection of nitroaromatic compounds at the ppm level in mix N,N′-dimethyl formamide-aqueous medium via the luminescence quenching mechanism.
关键词： furan-2,5-dicarboxylic acid,lanthanide coordination polymers,adipic acid,luminescent sensors,nitroaromatic compounds
更新于2025-09-23 15:21:01
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Color‐Based Optical Detection of Glass Transitions on Microsecond Timescales Enabled by Exciplex Dynamics
摘要： Every measurement technique operates on a given timescale and measurements using emissive small molecule sensors are no exception. A family of luminescent sensors providing first optical characterization of dynamic phenomena in polymers at a timescale of several microseconds is described. This performance originates from the dynamics manifested in the excited state of the sensor molecules where diffusioncontrolled events select the emission color while radiative phenomena define the global operation timescale. Since the mechanism responsible for signal generation is confined to the short lived excited state of emissive probe, it is possible observe an unprecedented link between the timescale of sensory action and that of photoluminescence. An application of this new methodology is demonstrated by performing general, short timescale detection of glass transitions in a temperature ranges precluding the informative range of conventional techniques by tens of degrees.
关键词： glass transition,copper,luminescent sensors,responsive polymers
更新于2025-09-11 14:15:04
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Terbium Oxalatophosphonate as Efficient Multiresponsive Luminescent Sensors for Chromate Anions and Tryptophan Molecules
摘要： A stable 2D terbium oxalatophosphonate with green luminescence, namely, [Tb2(H3L)(C2O4)3(H2O)4]·2H2O (1), has been hydrothermally obtained by using (4-carboxypiperidyl)-N-methylenephosphonic acid (H3L) and oxalate ligand. The luminescent investigation indicates that the emission behavior of compound 1 shows high water and pH stabilities. It can be applied as a multiresponsive luminescent probe with high selectivity, high sensitivity, recycling capability, and fast sensing of CrO42?, Cr2O72? anions and tryptophan (Trp) molecules in aqueous solution through the luminescence quenching effect. Moreover, the sensing results can be distinguished by the naked eye under the irradiation of UV light of 254 nm. In addition, the probable mechanisms for the quenching behavior are also discussed, which can be mainly attributed to the competitive absorption of excitation energy between compound 1 and the analytes.
关键词： chromate anions,luminescent sensors,competitive absorption,tryptophan molecules,terbium oxalatophosphonate
更新于2025-09-09 09:28:46