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Non-covalent Interaction Controlled 2D Organic Semiconductor Films: Molecular Self-Assembly, Electronic and Optical Properties, and Electronic Devices
摘要： The establishment of electronic and opto-electronic products relying on organic semiconductors (OSCs) has been intensely explored over the past few decades due to their great competitiveness in large area, low cost, flexible, wearable and implantable devices. Many of these products already entered our daily lives, such as organic light-emitting diodes-based displays, portable organic solar cells and organic field-effect transistors. The device performance of OSC devices are determined by the supramolecular organization (orientation, morphology) as well as the supramolecular organization dependent energy level alignment at various interfaces (organic/electrode, organic/dielectric, organic/organic). This review focuses on the impact of non-covalent interaction on the molecular self-assembly of organic thin films, their electronic and optical properties, as well as the device performance. Beginning with the growth of multiple OSCs on substrates with different interfacial interaction strengths (metals, insulators, semiconductors), the critical roles of molecule-substrate and intermolecular interactions in determining the thin film organization have been demonstrated. Several non-covalent interactions that contribute to the energy levels of organic materials in solid phase are summarized, mainly including the induction contributions, electrostatic interactions, band dispersions and interface dipoles. The excitonic coupling in specific aggregations of organic molecules and the corresponded effect on their optical properties are also discussed. Finally, the influences of weak intermolecular interactions on the device performance are presented.
关键词： molecular self-assembly,optical properties,non-covalent interaction,electronic properties,electronic devices,organic semiconductors
更新于2025-09-23 15:19:57
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Effects of Short‐Axis Alkoxy Substituents on Molecular Self‐Assembly and Photovoltaic Performance of Indacenodithiophene‐Based Acceptors
摘要： The effects of central alkoxy side chain length of a series of narrow bandgap small molecule acceptors (SMAs) on their physicochemical properties and on the photovoltaic performance of the SMA-based polymer solar cells (PSCs) are systematically investigated. It is found that the ordered aggregation of these SMAs in films is enhanced gradually with the increase of alkoxy chain length. The single-crystal structures of these SMAs further reveal that small changes in the side chain length can have a dramatic impact on molecular self-assembly. The short-circuit current density and power conversion efficiency values of the corresponding PSCs increase with the increase of the side chain length of the SMAs. The π–π coherence length of the SMAs in the active layers is increased with the increase of the side chain length, which could be the reason for the increase of the Jsc in the PSCs. The results indicate that small changes in side chain length can have a dramatic impact on the molecular self-assembly, morphology, and photovoltaic performance of the PSCs. The structure–performance relationship established in this study can provide important instructions for the side chain engineering and for the design of efficient SMAs materials.
关键词： polymer solar cells,side chain engineering,morphology,small molecule acceptors,molecular self-assembly
更新于2025-09-19 17:13:59