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Photo-oxidation of polypropylene/graphene nanoplatelets composites
摘要: The photo-oxidation behaviour of polymer nanocomposites depends not only on the photo-oxidation behaviour of the matrix, but also on the chemical composition, on the physical properties of the nanoparticles and on the possible interactions between the two phases. In the case of nanocomposites with carbonaceous particles, the main effect is a photo-stabilization due to the absorption of the UV energy and the radical scavenging action. In this work we investigated the effect of the presence of graphene nanoplatelets on the photo-oxidation behaviour of the polypropylene. The presence of the graphene nanoplatelets improves the photo-resistance of the polypropylene and this effect increases with the graphene content. This behaviour has been correlated with the exposed surface of the graphene and not to the dimensions of the graphene nanoplatelets.
关键词: Graphene nanoplatelets (GnP),Polypropylene,Photo-oxidation,Nanocomposites
更新于2025-09-04 15:30:14
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Giant Modal Gain Coefficients in Colloidal II-VI Nanoplatelets
摘要: Modal gain coefficient is a key figure of merit for a laser material. Previously, net modal gain coefficients larger than a few thousand cm-1 were achieved in II-VI and III-V semiconductor gain media, but this required operation at cryogenic temperatures. In this work, using pump-fluence-dependent variable-stripe-length measurements, we show that colloidal CdSe nanoplatelets enable giant modal gain coefficients at room temperature, up to 6,600 cm-1 under pulsed optical excitation. Furthermore, we show that exceptional gain performance is common to the family of CdSe nanoplatelets, as shown by examining samples having different vertical thicknesses and lateral areas. Overall, colloidal II-VI nanoplatelets with superior optical gain properties are promising for a broad range of applications, including high speed light amplification and loss compensation in plasmonic photonic circuits.
关键词: colloidal nanoplatelets,optical gain,variable stripe-length method,CdSe,modal gain coefficient,colloidal quantum wells
更新于2025-09-04 15:30:14