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Analysis of the Methods of Discrete and Smooth Frequency Tuning in Gyrotrons for Spectroscopy, on the Example of a Generator Operated in the 0.20–0.27 THz Frequency Range
摘要： We consider the main features of a low-power frequency-tunable gyrotron with an oversized cavity, which is designed for the purposes of nuclear magnetic resonance spectroscopy and other applications and operates in the 0.20–0.27 frequency range producing an output power of 200 W. We study the possibilities of wideband output frequency tuning by exciting a sequence of modes with similar caustics using magnetic-?eld variations and smooth tuning due to the excitation of modes with a great number of longitudinal variations. Aiming at widening the frequency tuning range, we also analyzed the possibility of smooth frequency tuning determined by controlled variations of the cavity temperature. Speci?c features of the electron-optical system of such a gyrotron is discussed, along with the possibility of increasing its e?ciency by means of single-stage recovery of the residual energy of the electron beam.
关键词： gyrotron,frequency tuning,nuclear magnetic resonance spectroscopy,electron-optical system,efficiency
更新于2025-09-10 09:29:36
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Ultrasonic Studies of Solid Azobenzene-Decorated Polymer Thin Films
摘要： This work investigates the effect of ultrasound on switching of cis azobenzene isomers to their trans counterparts in solid films of methyl methacrylate and methacryloyloxyazobenzene copolymers [P(MMA/MOAB)]. Ultraviolet?visible and 1H nuclear magnetic resonance spectroscopies demonstrate that 46% of the cis isomer converts to the trans form purely by ultrasonic agitation and 46% converts to the trans isomer by localized ultrasound-induced heating effects. Comparative studies of isomerization by ultrasound wave, heat, and visible irradiation show that ultrasound exposure requires a longer time to switch the cis-to-trans conformation. The estimated activation energy for the cis-to-trans conversion in solid polymer films is shown to be comparable to previous values of azobenzene isomerization, indicating that incorporation of the chromophore in a polymeric system affects the kinetics of transition but not the barriers to conformational change.
关键词： azobenzene,nuclear magnetic resonance spectroscopy,polymer thin films,ultrasound,isomerization,ultraviolet?visible spectroscopy
更新于2025-09-04 15:30:14