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Strategies towards rational design of gold(iii) complexes for high-performance organic light-emitting devices
摘要： Gold(iii) complexes are attractive candidates as phosphorescent dopants in organic light-emitting devices for high-luminance full-colour displays. However, no data on the stability of such devices have been reported to date. Through rational molecular design and synthesis, we have successfully generated a new class of cyclometalated gold(iii) C^C^N complexes with tunable emission colours spanning from sky-blue to red. These complexes exhibit high photoluminescence quantum yields of up to 80% in solid-state thin films, excellent solubility and high thermal stability. Solution-processable and vacuum-deposited organic light-emitting devices based on these complexes operate with external quantum efficiencies of up to 11.9% and 21.6%, respectively, and operational half-lifetimes of up to 83,000 h at 100 cd m?2.
关键词： operational stability,phosphorescent dopants,organic light-emitting devices,cyclometalated,gold(iii) complexes,C^C^N complexes
更新于2025-11-19 16:56:35
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Flexible and stable organic field-effect transistors using low-temperature solution-processed polyimide gate dielectrics
摘要： Polyimide (PI) has been widely used as a gate dielectric due to its remarkable thermal stability, chemical resistance, and mechanical flexibility. However, the high processing temperature and high surface energy of PI gate dielectrics hinder the realization of flexible and reliable electronic applications with low-cost manufacturing. Here, a low-temperature solution-processed organic field-effect transistor (OFET) is successfully demonstrated using a fully imidized soluble PI gate dielectric. The low temperature processability of soluble PI gate dielectrics is confirmed by investigating the effect of annealing temperature on the dielectric properties and electrical characteristics. By blending 6,13-Bis(triisopropylsilylethynyl)pentacene with polystyrene, the reliability of OFET is considerably enhanced while maintaining high device performance. As a result, OFETs exhibit excellent flexibility and can be integrated with ultrathin parylene substrates without degrading device performance. This work presents the steps to develop flexible and reliable electronic applications with low-cost manufacturing.
关键词： organic field-effect transistors,solution-processed,polyimides,low-temperature,operational stability
更新于2025-11-14 15:19:41
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Multi-component engineering to enable long-term operational stability of perovskite solar cells
摘要： With a record efficiency above 25%, the main hurdle for the commercialization of perovskite solar cells (PSCs) is their long-term operational stability. Although different strategies have been applied, the stability of PSCs is still far below the 25-year requirement demonstrated by commercial photovoltaic technologies. To advance in the former, a lab-scale stability analysis should resemble real testing conditions, and this is only possible through the interaction of several stress factors. Here, we briefly introduce the reader to the general degradation mechanisms observed on PSCs and the state-of-the-art strategies applied to realize long-term stable devices. Finally, we highlight the imperative need to engineer multiple components of the PSCs simultaneously and propose a rational design of PSC’s constituents to obtain long-term operational solar cells. This perspective article will benefit the progression of PSCs as a reliable photovoltaic technology.
关键词： multi-component engineering,perovskite solar cells,long-term operational stability
更新于2025-09-23 15:21:01
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A Thermally Induced Perovskite Crystal Control Strategy for Efficient and Photostable Widea??Bandgap Perovskite Solar Cells
摘要： Wide-bandgap perovskite solar cells (WBG PSCs) have gained attention as promising tandem partners for silicon solar cells due to their complementary absorption, superb open-circuit voltage, and easy solution process. Recently, both their performance and stability have been improved by compositional-engineering or defect-passivation strategies, due to modulation of perovskite crystal size and reduction of crystal defects. In this work, we report a thermally induced phase control (TIPC) strategy, which enables efficient and photostable WBG PSCs without any compositional engineering by exploring a thermal annealing process window of WBG perovskite films for the annealing temperature and time range of 100-175°C and 3-60 minutes, respectively. Within this window, we found a key annealing regime that produces preferred crystal orientations of lead iodide and the WBG perovskite, suppressing phase segregation and reducing charge recombination in the perovskites. The WBG PSC (composition of FA0.75MA0.15Cs0.1PbI2Br and Eg of 1.73 eV) optimized by TIPC exhibited an excellent power conversion efficiency (PCE) of 18.60% and improved operational stability, maintaining >90% of the maximum PCE (during maximum power point tracking) without encapsulation after 12-hour operation under AM 1.5G irradiation in ambient air conditions and after 500-hour operation under white LED irradiation (100 mW cm-2) in inert N2 gas conditions.
关键词： wide-band gap perovskite,thermal annealing process,operational stability,perovskite solar cells,invariant bandgap
更新于2025-09-23 15:21:01
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Enhanced operational stability through interfacial modification by active encapsulation of perovskite solar cells
摘要： Encapsulates are, in general, the passive components of any photovoltaic device that provides the required shielding from the externally stimulated degradation. Here we provide comprehensive physical insight depicting a rather non-trivial active nature, in contrast to the supposedly passive, atomic layer deposition (ALD) grown Al2O3 encapsulate layer on the hybrid perovskite [(FA0.83MA0.17)0.95Cs0.05PbI2.5Br0.5] photovoltaic device having the configuration: glass/FTO/SnO2/perovskite/spiro-OMeTAD/Au/(6) Al2O3. By combining various electrical characterization techniques, our experimental observations indicate that the ALD chemistry produces considerable enhancement of the electronic conductivity of the spiro-OMeTAD hole transport medium (HTM), resulting in electronic modification of the perovskite/HTM interface. Subsequently, the modified interface provides better hole extraction and lesser ionic accumulation at the interface, resulting in a significant lowering of the burn-in decay and nearly unchanged charge transport parameters explicitly under the course of continuous operation. Unlike the unencapsulated device, the modified electronic structure in the Al2O3 coated device is essentially the principal reason for better performance stability. Data presented in this communication suggest that the ionic accumulation at the spiro-OMeTAD/perovskite interface triggers the device degradation in the uncoated devices, which is eventually followed by material degradation, which can be avoided by active encapsulation.
关键词： encapsulation,Al2O3,atomic layer deposition,operational stability,perovskite solar cells
更新于2025-09-23 15:19:57
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Inverse Growth of Large Grain Size and Stable Inorganic Perovskite Micro-Nanowire Photodetectors
摘要： Control of the forward and inverse reactions between perovskites and precursor materials is key to attaining high quality perovskite materials. Many techniques focus on synthesizing nanostructured CsPbX3 materials (e.g., nanowires) via a forward reaction (CsX + PbX2 → CsPbX3). However, lower solubility of inorganic perovskites and complex phase transition make it difficult to realize the precise control of composition and the length of nanowires using the conventional forward approach. Herein, we report a self-assembly inverse growth of CsPbBr3 micro-nanowires (MWs) (CsPb2Br5 → CsPbBr3 + PbBr2 ↑) by controlling phase transition from CsPb2Br5 to CsPbBr3. Two-dimensional (2D) structure of CsPb2Br5 serves as nucleation sites to induce the initial CsPbBr3 MW growth. Also, phase transition allows crystal rearrangement and slows down the crystal growth, which facilitates the MW growth of CsPbBr3 crystals along the 2D planes of CsPb2Br5. A CsPbBr3 MW photodetector constructed based on the inverse growth shows a high responsivity of 6.44 A W-1 and detectivity of ~1012 Jones. Larger grain size, high crystallinity and bigger thickness can effectively alleviate the decomposition/degradation of perovskites, which leads to storage stability over 60 days in moisture (45% relative humidity) and operational stability over 3000 min under illumination (400 nm, ~20.06 mW cm-2).
关键词： inverse growth,photodetector,operational stability,inorganic perovskite,micro-nanowire
更新于2025-09-19 17:13:59
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Efficient Perovskite Solar Cell Modules with High Stability Enabled by Iodide Diffusion Barriers
摘要： Operational stability is crucial for the success in large-scale application of metal halide perovskites devices. The diffusion of volatile iodide component of perovskites can induce irreversible device degradation. Here, low-dimensional diffusion barriers were introduced to increase the operational stability of high-efficiency large-area PSC modules. A negligible decay was observed after 1,000 h under severe test condition for a 15% high-efficiency solar module.
关键词： Operational stability,Iodide diffusion,Large-area modules,Perovskite solar cells,Diffusion barriers
更新于2025-09-19 17:13:59
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What can we learn from model systems: Impact of polymer backbone structure on performance and stability of organic photovoltaics
摘要： We report the synthesis and extensive investigation of a broad family of novel (X-DADAD)n conjugated polymers with different X building blocks. It was shown that variation of X block in polymer backbone represents an efficient approach for tuning the polymer optical properties, frontier energy levels, charge transport characteristics as well as thin-film morphology and photovoltaic characteristics. Decent power conversion efficiencies (5.1–5.7%) were achieved for solar cells based on the polymers comprised of dibenzosilole (P2) and carbazole (P3) units. Polymers P2 and P3 showed impressive indoor and outdoor stability in solar cells while clearly outperforming common benchmark materials. In the view of the obtained results, the designed (X-DADAD)n polymers can be considered as promising semiconductor materials for stable organic photovoltaics.
关键词： Operational stability,Organic solar cells,Thiophene,Conjugated polymers,Benzothiadiazole
更新于2025-09-19 17:13:59
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Two-dimensional Ruddlesdena??Popper layered perovskite for light-emitting diodes
摘要： Solution-processed metal halide perovskite light-emitting diodes (PeLEDs) have attracted extensive attention due to the great potential application in energy-efficient lighting and displays. Two-dimensional Ruddlesden–Popper (2DRP) layered perovskites exhibit high photoluminescence quantum efficiency, improved film morphology, and enhanced operational stability over their three-dimensional counterparts, making them attractive for high-performance PeLEDs. In addition, 2DRP perovskite materials with a tunable exciton binding energy are suitable for preparing PeLEDs with color-tunability. In this perspective, we first introduce the merits of the 2DRP layered perovskites in terms of their structural characteristics. The progress in 2DRP PeLEDs is then reviewed. The challenges and new opportunities of the PeLEDs are finally discussed. We hope to open up new perspectives for rational designs of the 2DRP perovskite materials for PeLEDs with unprecedented efficiency and stability.
关键词： operational stability,film morphology,photoluminescence quantum efficiency,Two-dimensional Ruddlesden–Popper layered perovskite,color-tunability,light-emitting diodes
更新于2025-09-19 17:13:59
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Perovskite-molecule composite thin films for efficient and stable light-emitting diodes
摘要： Although perovskite light-emitting diodes (PeLEDs) have recently experienced significant progress, there are only scattered reports of PeLEDs with both high efficiency and long operational stability, calling for additional strategies to address this challenge. Here, we develop perovskite-molecule composite thin films for efficient and stable PeLEDs. The perovskite-molecule composite thin films consist of in-situ formed high-quality perovskite nanocrystals embedded in the electron-transport molecular matrix, which controls nucleation process of perovskites, leading to PeLEDs with a peak external quantum efficiency of 17.3% and half-lifetime of approximately 100 h. In addition, we find that the device degradation mechanism at high driving voltages is different from that at low driving voltages. This work provides an effective strategy and deep understanding for achieving efficient and stable PeLEDs from both material and device perspectives.
关键词： perovskite light-emitting diodes,external quantum efficiency,perovskite-molecule composite thin films,operational stability
更新于2025-09-19 17:13:59