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Ultralong Lifetime Room Temperature Phosphorescence and Dual-band Waveguide Behavior of Phosphoramidic Acid Oligomers
摘要： In recent years, some natural or synthetic non-conjugated luminescence systems have attracted much attention. However, the phosphorescent properties of these materials are generally not very satisfactory due to the lack of special molecular design. In this work, the phosphoramidic acid is introduced into the oligomer matrix to construct a non-conjugated photoluminescence system with ultralong phosphorescence lifetime up to 376.5 to 776.9 ms and high phosphorescence quantum yield (4.6-10.5 %). At the same time, the new system also displays good thermo-processing properties, vitreous solid and optical waveguide behavior.
关键词： Room temperature phosphorescence,ultralong phosphorescence lifetime,phosphoramidic acid oligomers,optical waveguide behavior
更新于2025-09-23 15:21:01
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Physicala??Chemical Properties of Self-Assembled Structures in Solution of Zinc Phthalocyanine and Bis-3-pentyl-PTCDI Derivative
摘要： For the first time, in this work, we succeed in synthesizing in solution a novel supramolecular self-assembled zinc phthalocyanine (ZnPc) and N,N′-bis(3-pentyl)-perylene-3,4,9,10-bis(dicarboximide) (bis-3-pentyl-PTCDI) system with improved light absorption and phosphorescence lifetime of the charge separated states up to 2.5 ms. Moreover, the structural and optical properties of undoped and doped with iodine ZnPc thin films were investigated by X-ray diffraction, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, Raman analysis, and UV?vis spectroscopy. Analysis of ZnPc:I2:bis-3-pentyl-PTCDI blend in a 2:1 ratio shows that sandwich complexes between them result in improved bulk properties as compared to those of the single-component systems.
关键词： light absorption,Fourier transform infrared spectroscopy,UV?vis spectroscopy,bis-3-pentyl-PTCDI,X-ray diffraction,supramolecular self-assembly,X-ray photoelectron spectroscopy,zinc phthalocyanine,phosphorescence lifetime,Raman analysis
更新于2025-09-23 15:19:57
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Fast repetition rate fs pulsed lasers for advanced PLIM microscopy
摘要： Simultaneous metabolic and oxygen imaging is promising to follow up therapy response, disease development and to determine prognostic factors. FLIM of metabolic coenzymes is now widely accepted to be the most reliable method to determine cellular bioenergetics. Also, oxygen consumption has to be taken into account to understand treatment responses. The phosphorescence lifetime of oxygen sensors is able to indicate local oxygen changes. For phosphorescence lifetime imaging (PLIM) dyes based on ruthenium (II) coordination complexes are useful, in detail TLD1433 which possesses a variety of different triplet states, enables complex photochemistry and redox reactions. PLIM is usually reached by two photon excitation of the drug with a femtosecond (fs) pulsed Ti:Sapphire laser working at 80 MHz repetition rate and (time-correlated single photon counting) (TCSPC) detection electronics. The interesting question was whether it is possible to follow up PLIM using faster repetition rates. Faster repetition rates could be advantageous for the induction of specific photochemical reactions because of similar light doses used normally in standard CW light treatments. For this, a default 2p-FLIM–PLIM system was expanded by adding a second fs pulsed laser ("helixx") which provides 50 fs pulses at a repetition rate of 250 MHz, more than 2.3 W average power and tunable from 720 nm to 920 nm. The laser beam was coupled into the AOM instead of the default 80 MHz laser. We demonstrated successful applications of the 250 MHz laser for PLIM which correlates well with measurements done by excitation with the conventional 80 MHz laser source.
关键词： oxygen consumption,Ru(II) complexes,phosphorescence lifetime microscopy,Multiphoton microscopy,fast repetition rate excitation,short laser pulses
更新于2025-09-11 14:15:04