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oe1(光电查) - 科学论文

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出版时间
  • 2019
  • 2018
  • 2014
研究主题
  • solar cell
  • hybrid-resonant PWM switching
  • PWM switching
  • MPPT
  • resonant converter
  • solar power
  • Geostationary satellite images
  • Global and direct solar radiation
  • Meteorological station
  • validation
应用领域
  • Electrical Engineering and Automation
  • New Energy Science and Engineering
  • Optoelectronic Information Science and Engineering
  • Optoelectronic Information Materials and Devices
  • Applied Physics
机构单位
  • National technical University “Kharkiv Polytechnic Institute”
  • University of évora
  • Fraunhofer Institute for Solar Energy Systems ISE
  • University of Tunis El Manar
  • Zeal College of Engineering and Research
  • Northern (Arctic) Federal University named after M.V. Lomonosov
  • Cochin University College of Engineering
  • National Renewable Energy Laboratory
  • NED University
  • Universidad Veracruzana
4089 条数据
?? 中文（中国） ▾

  • Transparent Platinum Counter Electrode Prepared by Polyol Reduction for Bifacial, Dye-Sensitized Solar Cells

    摘要： Pt catalytic nanoparticles on F-doped SnO2/glass substrates were prepared by polyol reduction below 200 °C. The polyol reduction resulted in better transparency of the counter electrode and high power-conversion efficiency (PCE) of the resultant dye-sensitized solar cells (DSSCs) compared to conventional thermal reduction. The PCEs of the DSSCs with 5 μm-thick TiO2 photoanodes were 6.55% and 5.01% under front and back illumination conditions, respectively. The back/front efficiency ratio is very promising for efficient bifacial DSSCs.

    关键词： dye-sensitized solar cell,platinum,bifacial,ethylene glycol,counter electrode

    更新于2025-11-21 11:01:37

  • g-C3N4 nanosheets functionalized silicon nanowires hybrid photocathode for efficient visible light induced photoelectrochemical water reduction

    摘要： We report the fabrication of hybrid Si nanowires @ g-C3N4 nanosheets based photocathode using metal assisted chemical etching and facile liquid exfoliated process. The g-C3N4 nanosheets on Si nanowires form hybrid heterojunction photocathode, which exhibits an enhanced photon induced water reduction activity enabling higher photocurrent density of 22 mA cm?2 with applied bias photocurrent conversion efficiency of 4.3% under visible light irradiation. The onset potential of cathodic photocurrent is positively shifted from 41 to 420 mV vs. RHE with the short circuit current density, Jsc of 0.50 mA cm?2 owing to superior charge transport in hybrid photocathode as compared to pristine Si nanowires for hydrogen evolving reaction at pH～7. The electrochemical impedance spectroscopy measurement elucidates the interface layer of g-C3N4 nanosheets form hybrid heterojunction with Si nanowires that result significant increment in solar water reduction activity owing to low charge transferred resistance with high life time of excited electrons in conduction band. This strategy may open to design a new low cost stable hybrid heterostructure photocathode for solar induced water reduction.

    关键词： Solar water reduction,Si nanowires,Photocathode,g-C3N4 nanosheets,Interface

    更新于2025-11-21 11:01:37

  • Coral-Like Perovskite Nanostructures for Enhanced Light-Harvesting and Accelerated Charge Extraction in Perovskite Solar Cells

    摘要： A novel coral-like perovskite nanostructured layer was grown on a compact perovskite foundation layer by the facile surface modification with dimethylformamide/isopropanol (DMF/IPA) as co-solvent. Surface morphological characterizations with SEM and XRD analyses revealed a growing mechanism of the new morphology, which was composed of the perovskite decomposition and recrystallization, excessive-PbI2 extraction, and sequential formation of coral-like nanostructured perovskite layer. The coral-like perovskite nanostructures resulted in significant light scattering, enhancing the light harvesting efficiency, and thus augmenting the photocurrent density. Moreover, the geometric configuration of the perovksite solar cells was changed from planar to bulk heterojunction, which results in the acceleration of charge separation and extraction due to the high surface area at the interface between the obtained perovskite and hole-transport layers. The optimal perovskite solar cell exhibited an impressive power conversion efficiency (PCE) of 19.47%, as compared to that of the pristine cell (17.19%).

    关键词： solar cells,Bulk heterojunction,light-harvesting,coral-like nanostructures,surface modification,perovskite

    更新于2025-11-21 11:01:37

  • UV-ozone induced surface passivation to enhance the performance of Cu2ZnSnS4 solar cells

    摘要： Interface property has been considered one of the most critical factors affecting the performance of semiconductor devices. In this work, we demonstrate an efficient surface passivation for the interface between Cu2ZnSnS4 (CZTS) and CdS buffer layer by using UV-ozone treatment at room temperature. The passivation led to a significant enhancement of short circuit current density (Jsc) of the device from 11.70 mA/cm2 to 18.34 mA/cm2 and thus efficiency of the CZTS solar cells from 3.18% to 5.55%. The study of surface chemistry has revealed that the UV-ozone exposure led to formation of a Sn–O rich surface on CZTS, which passivates the dangling bonds and forms an ultra-thin energy barrier layer at the interface of CZTS/CdS. The barrier is considered to be responsible for the reduction of non-radiative recombination loss in the solar cells as confirmed by photoluminescence (PL) measurement. The elongated lifetime of minority carriers in the CZTS solar cells by time-resolved PL has further verified the interface passivation effect induced by UV-ozone treatment. This work provides a fast, simple yet very effective approach for surface passivation of CZTS film to boost the performance of CZTS solar cells.

    关键词： CZTS solar cell,UV-Ozone treatment,Interface modification,Surface passivation

    更新于2025-11-21 11:01:37

  • Surface Passivation of Perovskite Solar Cells Toward Improved Efficiency and Stability

    摘要： The advancement of perovskite solar cells (PVSCs) technology toward commercialized promotion needs high efficiency and optimum stability. By introducing a small molecular material such as tetratetracontane (TTC, CH3(CH2)42CH3) at the fullerene (C60)/perovskite interface of planar p-i-n PVSCs, we significantly reduced the interfacial traps, thereby suppressing electron recombination and facilitating electron extraction. Consequently, an improved efficiency of 20.05% was achieved with a high fill factor of 79.4%, which is one of the best performances for small molecular-modified PVSCs. Moreover, the hydrophobic TTC successfully protects the perovskite film from water damage. As a result, we realized a better long-term stability that maintains 87% of the initial efficiency after continuous exposure for 200 h in air.

    关键词： Surface defect,Charge transport,Surface passivation,Perovskite solar cells

    更新于2025-11-21 11:01:37

  • Nano-mirror embedded back reflector layer (BRL) for advanced light management in thin silicon solar cells

    摘要： This work illustrates a technology for advanced light management by introducing a nonconventional back reflector layer (BRL) in amorphous silicon (a-Si:H) solar cells. To meet this, silver sulfide (Ag2S) nanoparticles with ~50 nm diameter have been chosen as the nano-mirror owing to its low parasitic absorption loss over a broad wavelength (300 to 1100 nm) region. The Ag2S NPs were sandwiched between two indium tin oxide (ITO) layer and placed as the back reflector layer of an a-Si:H solar cell to achieve better light trapping within the active layers. The embedded structure exhibited high reflectance (up to 93%) in the red and near-infrared region, the main working zone of a-Si:H cells. With the incorporation of such state of the art back reflector structure in a-Si:H solar cells, a photo-conversion efficiency of 10.58% has been achieved; which is one of the best in this class.

    关键词： a-Si:H solar cell,Back reflection,theoretical validation,high efficiency,nano-mirror

    更新于2025-11-21 11:01:37

  • Ultra-flexible perovskite solar cells with crumpling durability: toward a wearable power source

    摘要： Perovskite materials hold great potential as photovoltaic power sources for portable devices owing to their mechanical flexibility and high performance; however, the flexibility and e?ciency require further improvement to attain practical viability. We investigated the mechanical fracture behavior of polycrystalline perovskite films by varying the substrate thickness and applying the neutral plane concept. This enabled us to fabricate a crack-free perovskite film on an ultra-thin substrate (B2.5 mm) and to demonstrate ultra-flexible solar cells with high e?ciency (17.03%) with unprecedented flexibility sustained after 10 000 cycles of bending at a 0.5 mm radius. This represents a high e?ciency of 13.6% for large-area flexible perovskite solar cells (1.2 cm2), fabricated by using a hybrid transparent electrode composed of a metal mesh grid and conducting polymer. Using a protective layer to achieve the neutral plane concept, our ultra-flexible perovskite solar cells are demonstrated to be durable even after 100 crumpling cycles. Our approach paves the way to fabricate flexible perovskite solar cells for portable power sources.

    关键词： wearable power source,Perovskite solar cells,mechanical durability,neutral plane concept,flexible

    更新于2025-11-21 10:59:37

  • Cu(In,Ga)Se2 monograin powders with different Ga content for solar cells

    摘要： Monograin layer (MGL) solar cell technology based on CuIn1-xGaxSe2 (CIGSe) monograin powder crystals is a promising approach for the future low-cost production of flexible solar panels. In this study, CuIn1-xGaxSe2 monograin powders (0 ≤ x ≤ 1) were prepared from binary compounds in the liquid phase of potassium iodide as flux material in evacuated quartz ampoules at 720 °C. The crystal structure and the lattice parameters of the CIGSe monograin powder crystals were determined by using X-ray diffraction analysis. A linear decrease of the lattice parameters with increasing Ga concentration was detected. The photoluminescence (PL) spectra of the CIGSe crystals were dominated by the edge emission band that shifted towards higher energies with increasing Ga content. Moreover, additional deep PL band (below 1.0 eV) appeared for Ga contents above x = 0.21 showing higher relative intensity with increasing Ga content. The effective bandgap energy of the CIGSe monograin powder materials ranged from 1.0 eV to 1.68 eV as the [Ga]/([In] + [Ga]) ratio increased from 0 to 1.0. An efficiency of 12.8% (active area) was obtained with the MGL solar cell based on CuIn1-xGaxSe2 monograin powder with Ga content of x = 0.21.

    关键词： Cu(In,Ga)Se2,Solar cell,Crystalline powder,Crystal growth

    更新于2025-11-21 10:59:37

  • Understanding the Impact of Cu-In-Ga-S Nanoparticles Compactness on Holes Transfer of Perovskite Solar Cells

    摘要： Although a compact holes-transport-layer (HTL) ?lm has always been deemed mandatory for perovskite solar cells (PSCs), the impact their compactness on the device performance has rarely been studied in detail. In this work, based on a device structure of FTO/CIGS/perovskite/PCBM/ZrAcac/Ag, that effect was systematically investigated with respect to device performance along with photo-physics characterization tools. Depending on spin-coating speed, the grain size and coverage ratio of those CIGS ?lms on FTO substrates can be tuned, and this can result in different hole transfer ef?ciencies at the anode interface. At a speed of 4000 r.p.m., the band level offset between the perovskite and CIGS modi?ed FTO was reduced to a minimum of 0.02 eV, leading to the best device performance, with conversion ef?ciency of 15.16% and open-circuit voltage of 1.04 V, along with the suppression of hysteresis. We believe that the balance of grain size and coverage ratio of CIGS interlayers can be tuned to an optimal point in the competition between carrier transport and recombination at the interface based on the proposed mechanism. This paper de?nitely deepens our understanding of the hole transfer mechanism at the interface of PSC devices, and facilitates future design of high-performance devices.

    关键词： perovskite solar cells,compactness,Cu-In-Ga-S,hole transfer,holes transport layer,recombination

    更新于2025-11-21 10:59:37

  • Transparent Sn-doped In2O3 electrodes with a nanoporous surface for enhancing the performance of perovskite solar cells

    摘要： We report on a simple and efficient process to enhance the performance of perovskite solar cells by using ITO electrodes with a nanoporous surface formed by wet-etching of self-agglomerated Ag nanoparticles. Effective removal of the Ag nanoparticles embedded in the surface of the ITO electrodes result in a nanoporous structure without changing the ITO's sheet resistance (10.17 Ω/square) and optical transmittance (89.08%) at a 550 nm wavelength. Examinations with a scanning electron microscope, a transmission electron microscope, and two-dimensional porous mapping show that the nanoporous ITO surface has an increased contact area with the electron transport layer, which enhanced the carrier extraction efficiency of the perovskite solar cells. Compare to perovskite solar cells fabricated on typical ITO with a flat surface morphology, the perovskite solar cells fabricated on the nanoporous-surface ITO show a higher fill factor of 81.1% and a power conversion efficiency of 20.1%. These results indicate that modified ITO surfaces with nano-scale porosity provide a simple and efficient method to improve the power conversion efficiency of perovskite solar cells without a complicated process.

    关键词： Contact area,Nanoporous surface,Sn-doped In2O3,Ag agglomeration,Perovskite solar cells

    更新于2025-11-21 10:59:37