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Optimization of Non-Orthogonal Multiple Access based Visible Light Communication Systems
摘要： In Visible Light Communication (VLC), the data is transmitted by modulating the Light Emitting Diode (LED). The data-rate is throttled by the narrow modulation bandwidth of LEDs which results as a barrier in attaining high transmission rates. Non-Orthogonal Multiple Access (NOMA) is a new Multiple Access (MA) scheme envisioned to improve the system capacity. In addition to MA schemes, optimization techniques are applied to further improve the data-rate. In this letter, convex optimization is applied on NOMA-based VLC system for downlinks. The proposed optimization system is analyzed in terms of the Bit Error Rate (BER) and the sum-rate.
关键词： Sum-rate maximization,Visible Light Communication,Non-Orthogonal Multiple Access (NOMA),Convex Optimization,5G
更新于2025-09-23 15:23:52
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[IEEE 2018 IEEE 3rd Optoelectronics Global Conference (OGC) - Shenzhen (2018.9.4-2018.9.7)] 2018 IEEE 3rd Optoelectronics Global Conference (OGC) - High Speed Novel Hybrid Modulation Technique of Visible Light Communication Based on Artificial Neural Network Equalizer
摘要： Visible light communication (VLC) which realizes data transmission and universal illumination simultaneously has attracted much attention recently. However, the transmission rate of the VLC remains low due to the low bandwidth performance and inter-symbol interference (ISI). Therefore, a hybrid approach using pulse amplitude modulation and pulse width modulation in conjunction with an artificial neural network (ANN) equalizer is proposed, which can theoretically increase the transmission rate by 4 times compared with the traditional way, and provide variable brightness to realize the integration of data transmission and illumination control. In addition, an artificial neural network equalizer is proposed to undo the effects of ISI, considering that the bandwidth of the LED is only 3MHz. Without the ANN equalizer, the maximum transmission rate of the proposed hybrid modulation link only reaches 36 Mbps under the condition of no signal processing; however, with the ANN equalizer, the transmission speed can up to 2.6 Gbps. The proposed system not only achieves a genuine combination of data transmission and control illumination levels, but also realizes a high data rate with less complexity.
关键词： code division multiple access,pulse amplitude modulation,visible light communication,artificial neural network equalizer
更新于2025-09-23 15:23:52
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Facile fabrication of phosphorus-doped g-C3N4 exhibiting enhanced visible light photocatalytic degradation performance toward textile dye
摘要： Phosphorus-doped graphitic carbon nitride (P-g-C3N4) was facilely fabricated by in situ thermal copolymerization of urea and triphenylphosphine source materials. The P-g-C3N4 exhibited an enhanced photocatalytic performance than pristine g-C3N4 counterpart for the degradation of rhodamine B and acid blue D-2BR textile dye under visible light irradiation. X-ray diffraction (XRD), transmission electron microscopy (TEM), N2 adsorption-desorption isotherms, X-ray photoelectron spectra (XPS), and diffuse reflection spectroscopy (DRS) techniques were used to characterized the structure and property of P-g-C3N4 photocatalyst. The phosphorus doping enhanced visible light harvesting and surface area, but also substantially changed the electronic property of g-C3N4 material that could suppress the recombination of photogenerated charge carriers, and thus improved photocatalytic performance.
关键词： Textile dye,Porous photocatalyst,Visible light,Degradation,Phosphorus-doped g-C3N4
更新于2025-09-23 15:23:52
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Effect of Co component in Co-Ag granular thin films on visible-light reflection applied by magnetic field
摘要： The reflection of visible light (wavelength from 350 to 800 nm) on magnetic granular thin films Cox-Ag1-x with x from 0 to 35 at % was studied. Dependence of reflection (R) is strong on magnetic and percentage of Co in the thin films, R strongly increase in wavelengths 560 and 660 nm. In this paper, some arguments relating to the spin-plasmon phenomenon were used to explain the results.
关键词： spin-plasmon,Granular magnetic thin films,visible light,reflection
更新于2025-09-23 15:23:52
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Nanocrystal-engineered thin CuO film photocatalyst for visible-light-driven photocatalytic degradation of organic pollutant in aqueous solution
摘要： We design a thin CuO film photocatalyst for visible-light-driven photocatalytic degradation of methylene blue (MB). Nanocrystal engineering of the photocatalyst is performed by sputtering with concurrent in-situ thermal treatment. The impacts of the in-situ thermal treatment temperature and sputtering conditions on the material properties of the thin CuO film photocatalyst are investigated in detail. Systematic characterization using field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) indicates that deposition at elevated temperature and higher sputtering power significantly improves the surface structure and crystallinity of thin CuO film, which promotes charge transfer and ultimately results in better performance for MB photocatalytic degradation. The best-performing sample is the one sputtered at an elevated temperature of 300 °C and a sputtering power of 300 W. The photodegradation efficiency and physical durability of the samples were also analyzed after using for 5 cycles. The results indicate that in-situ thermal treatment and nanocrystal engineering of the thin CuO film significantly improve the physical durability.
关键词： Thin CuO film photocatalyst,Visible-light-driven photocatalytic degradation,Nanocrystal engineering
更新于2025-09-23 15:23:52
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Visible Light Driven Hydrogen Evolution by Molecular Nickel Catalysts with Time-Resolved Spectroscopic and DFT Insights
摘要： Hydrogen (H2) is a clean fuel that can potentially be a future solution for the storage of intermittent renewable energy. However, current H2 production is mainly dominated by the energy intensive steam reforming reaction, which consumes a fossil fuel, methane, and emits copious amounts of carbon dioxide as one of the byproducts. To address this challenge, we report a molecular catalyst that produces H2 from aqueous solutions, is composed of affordable, earth-abundant elements such as nickel, and has been incorporated into a system driven by visible light. Under optimized conditions, we observe a turnover number of 3880, among the best for photocatalytic H2 evolution with nickel complexes from water?methanol solutions. Through nanosecond transient absorption, electron paramagnetic resonance, and UV?vis spectroscopic measurements, and supported by density functional theory calculations, we report a detailed study of this photocatalytic H2 evolution cycle. We demonstrate that a one-electron reduced, predominantly ligand-centered, reactive Ni intermediate can be accessed under visible light irradiation using triethylamine as the sacrificial electron donor and reductive quencher of the initial photosensitizer excited state. In addition, the computational calculations suggest that the second coordination sphere ether arms can enhance the catalytic activity by promoting proton relay, similar to the mechanism among [FeFe] hydrogenases in nature. Our study can form the basis for future development of H2 evolution molecular catalysts that incorporate both ligand redox noninnocence and alternative second coordination sphere effects in artificial photosynthetic systems driven by visible light.
关键词： Proton relay,Second coordination sphere,DFT calculations,Time-resolved spectroscopy,Visible light photocatalysis,Hydrogen evolution,Molecular nickel catalysts
更新于2025-09-23 15:23:52
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Facile synthesis of N/B double-doped Mn <sub/>2</sub> O <sub/>3</sub> and WO <sub/>3</sub> nanoparticles for dye degradation under visible light
摘要： In the present work, Nitrogen-doped and Nitrogen-Boron double doped manganese oxide (Mn2O3) and tungsten oxide (WO3) nanoparticles were synthesized using precipitation-hydrothermal method for methylene blue degradation under visible light. Materials were characterized using X-ray diffraction (XRD) analysis, Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDX) and UV-Vis spectroscopy. Results showed that N and B were successfully incorporated into the crystal lattices of Mn2O3 and WO3. XRD showed that WO3 was crystallized in the form of a monoclinic lattice, while cubic Mn2O3 was produced in the cubic form. The crystallite size was found to be decreased due to the substitution of N and B elements which reveals their roles to accelerate the crystal nucleation rate resulting in the decreased size. On the other hand, single and double doping has successfully narrowed the bandgaps of the as-synthesised metal oxide photocatalysts resulting in better absorption in the visible light. Bandgaps obtained were as follows: 3.02, 2.50, 1.73 and 1.77 eV for N-WO3 N/B-WO3, N-Mn2O3 and N/B-Mn2O3 respectively. Photocatalytic experiments showed that all as-synthesised materials exhibited a photocatalytic efficiency under visible light ≥420 nm. The degradation efficiency of MB was in the following order: N-B-co-doped metal oxides > N-doped metal oxides > metal oxides. The presence of scavenger molecules such as isopropanol (IPA), EDTA-2Na and benzoquinone inhibited MB degradation. Finally, the results showed that these materials can be reused several times without a notable decrease in efficiency.
关键词： Photocatalytic degradation,Visible light,Double-doping,Metal oxides
更新于2025-09-23 15:23:52
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Construction of Strontium Titanate/Binary Metal Sulfide Heterojunction Photocatalysts for Enhanced Visible-Light-Driven Photocatalytic Activity
摘要： A novel strontium titanate/binary metal sulfide (SrTiO3/SnCoS4) heterostructure was synthesized by a simple two-step hydrothermal method. The visible-light-driven photocatalytic performance of SrTiO3/SnCoS4 composites was evaluated in the degradation of methyl orange (MO) under visible light irradiation. The photocatalytic performance of SrTiO3/SnCoS4-5% is much higher than that of pure SrTiO3, SnCoS4, SrTiO3/SnS2 and SrTiO3/CoS2. The SrTiO3/SnCoS4 composite material with 5 wt.% of SnCoS4 showed the highest photocatalytic efficiency for MO degradation, and the degradation rate could reach 95% after 140 min irradiation time. The enhanced photocatalytic activity was ascribed to not only the improvement of visible light absorption efficiency, but also the construction of a heterostructure which make it possible to effectively separate photoexcited electrons and holes in the two-phase interface.
关键词： visible-light-driven,SnCoS4,heterojunction,degradation,SrTiO3
更新于2025-09-23 15:23:52
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Constructing 3D sub-micrometer CoO octahedrons packed with layered MoS2 shell for boosting photocatalytic overall water splitting activity
摘要： A 3D architectures of CoO@MoS2 composite photocatalyst was prepared by coating MoS2 onto the (1 1 1) facts of sub-micrometer CoO octahedrons via a facile solvothermal method. The CoO@MoS2 composites show a significantly improved photocatalytic activity for overall water splitting. At an optimal ratio of 3 wt% MoS2, CoO@MoS2-3% composite can split pure water with the stoichiometric ratio production of H2 and O2 under visible light irradiation, meanwhile, presents the highest H2 production evolution (1.07 μmol/h), which is almost four times than that of pure CoO (0.26 μmol/h). Moreover, the CoO@MoS2 composite still remains good stability after three successive cyclings (over 72 h). The enhanced photocatalytic activity and stability can be attributed that the layered MoS2 shell not only promoted the photo-induced charge transfer at the interface of CoO due to the sufficient contact area between CoO and MoS2, but also protected the exposed the (1 1 1) facts of CoO from devastation. Our work offers more insights into the development of a simple synthesis of well-shaped 3D-based composite photocatalysts towards the energy- and environmental-related applications.
关键词： CoO octahedrons,MoS2,Overall water splitting,Core-shell,Visible light
更新于2025-09-23 15:23:52
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Layered Adaptive Collaborative Constellation for MIMO Visible Light Communication
摘要： In this paper, we propose a novel technique to effectively design a channel adaptive collaborative constellation called the layered adaptive collaborative constellation (LACC) for multiple-input multiple-output visible light communications. Recently, a channel-adaptive space-collaborative constellation (CASCC) that designs the constellation with the consideration of channel into the model to improve the receiver mobility and enhance the error performance. However, this scheme only considers into optimization four constellation points that form a diamond shape in the receiver space. Our proposed scheme effectively exploits the layered structure of collaborative constellation and overcomes the aforementioned drawbacks of CASCC. Furthermore, an improved low-complexity maximum likelihood (ML)-based detector is derived. Simulation results show that the LACC can achieve some performance gain, compared with previous constellation design schemes for different scenarios, especially really high-correlation channels and under imperfect channel state information. Moreover, the proposed detector drastically reduces computational complexity while maintaining the same performance as a traditional ML detector.
关键词： maximum likelihood (ML) detection,multiple-input multiple-output (MIMO),Visible light communications (VLC),space collaborative constellation
更新于2025-09-23 15:23:52