研究目的
To synthesize low-cost carbon modified TiO2 counter electrodes for high-efficiency dye-sensitized solar cells.
研究成果
A simple and effective method was used to synthesize carbon modified TiO2 counter electrodes for high-efficiency dye-sensitized solar cells. The photoelectric conversion efficiency of DSSCs is near that of the referenced Pt counter electrode. This method is a truly simple method to fabricate high activity counter electrodes on a large scale for widespread practical DSSCs.
研究不足
The reaction between carbon and the leaked oxygen is more active at higher annealing temperature, which decreases the efficiency.
1:Experimental Design and Method Selection:
The TiO2 paste was screen-printed on fluorine doped tin oxide (FTO) glass and annealed under Ar flow to form carbon coated TiO2 nanoparticles.
2:Sample Selection and Data Sources:
The TiO2 paste was purchased from Greatcell Solar Limited (GSL 90-T-20 nm).
3:List of Experimental Equipment and Materials:
FESEM, FEI Inspect F50; XRD, Rigaku Smartlab; TEM, Tecnai G2 F20 TEM; electrochemical workstation, CHI760D.
4:0D. Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: The TiO2 paste was screen-printed on FTO glass, annealed under Ar flow, and used as a counter electrode in DSSCs.
5:Data Analysis Methods:
The performance of the DSSCs was characterized under AM 1.5 G simulated sunlight.
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FESEM
FEI Inspect F50
FEI
Characterization of the morphology of the as-grown samples.
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XRD
Rigaku Smartlab
Rigaku
Measurement of the crystal structures of the counter electrode.
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Electrochemical workstation
CHI760D
CHI
Electrochemical characterizations.
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TiO2 paste
GSL 90-T-20 nm
Greatcell Solar Limited
Used for screen-printing on FTO glass substrate to form the counter electrode.
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TEM
Tecnai G2 F20 TEM
Tecnai
Taking transmission electron microscope images.
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