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Effect of Decomposition of CuO Film on Ignition of Organic Explosives by a Laser Pulse

DOI:10.1002/prep.201900047 期刊:Propellants, Explosives, Pyrotechnics 出版年份:2019 更新时间:2025-09-11 14:15:04
摘要: This work presents experimental results of the PETN ignition in a three-layer system: glass – copper oxide (CuO) – explosive materials (EM) and results of numerical simulations of the ignition of PETN, RDX, HMX, and TATB with a CuO film heated by a YLS-150 fiber laser with a pulse duration of 20 ms. In the numerical simulations, the endothermic reaction of decomposition of the CuO film and decomposition reaction of EM were taken into account. It has been established that the endothermic effect of the CuO decomposition reaction increases the dynamic ignition delay time of EM. The expression for an estimation of width of a reaction layer in EM at heating by a constant heat stream is obtained. Calculations have shown that the dynamic threshold of ignition of organic explosives by laser pulse in a three-layer system (glass – CuO – EM) has a minimum for the thickness of the copper oxide film of 5 mm. The density of the critical ignition energy of an explosive laser pulse increases in the sequence of PETN, RDX, HMX, and TATB. The calculated dependence of the PETN dynamic ignition delay time on the thickness of the CuO film is consistent with the experimental data.
作者: Alexander Khaneft,Anatoly Mitrofanov,Anton Zverev
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To perform numerical simulations of the ignition of organic EM (PETN, RDX, HMX, and TATB) with a CuO film heated by a YLS-150 millisecond fiber laser in a three-layer system of glass – CuO – EM taking into account the endothermic decomposition reaction of the CuO film and the EM burn-out.

The endothermic effect of the CuO decomposition reaction increases the dynamic time of EM ignition delay. The calculated dependence of the dynamic time of ignition delay PETN on the thickness of the film CuO agrees with the experimental data. The dynamic threshold of ignition of organic explosives by laser pulse in a three-layer system (glass – CuO – EM) has a minimum for the thickness of the copper oxide film of 5 mm.

The study did not account for the change in reflection and absorption coefficients due to thermal decomposition of the CuO film. It also assumed that the heat conductivity and heat capacity of the resulting EM melt and its solid phase differ insignificantly. The external heat sink was neglected due to the short duration of the laser pulse and the time of ignition delay.

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