研究目的
To further improve the quantum-cutting efficiency of Yb3+ in perovskite quantum dots (PQDs) and expand its applications in solar energy area.
研究成果
The Yb3+, Pr3+, Ce3+ tri-doped CsPbClBr2 PQDs demonstrated a high PLQY of 173% and were successfully applied to enhance the PCE of CIGS and silicon solar cells by ~20%. This work provides a universal and effective way to improve the performance of photovoltaic solar cells.
研究不足
The long-term stability of PQDs under continuous irradiation and in the air needs improvement. The PLQYs and PCEs could be further optimized.
1:Experimental Design and Method Selection:
The Yb3+-Ln3+ (Ln=Nd, Dy, Tb, Pr, Ce) pairs doped CsPbClxBryI3-x-y PQDs were fabricated via a modified hot-injection method and anion-exchange reactions.
2:Sample Selection and Data Sources:
The samples were characterized by TEM, XRD, XPS, and PL measurements.
3:List of Experimental Equipment and Materials:
Transmission electron microscope (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), photoluminescence (PL) measurements.
4:Experimental Procedures and Operational Workflow:
The PQDs were synthesized and then characterized for their structural, morphological, and optical properties. The performance of solar cells coated with PQDs was evaluated.
5:Data Analysis Methods:
The data were analyzed to determine the PLQYs, PCEs, and other optical and electrical properties.
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