研究目的
Investigating the effect of adding PC71BM fullerene as an electron acceptor into the polymer donor of P3HT and the small molecular non-fullerene acceptor of IEICO-4F host system on the performance of panchromatic organic photodetectors (OPDs).
研究成果
The addition of PC71BM fullerene acceptor into the P3HT:IEICO-4F system significantly improved the performance of panchromatic OPDs, achieving a high detectivity of 1.35 × 1012 Jones at 805 nm. This improvement was attributed to enhanced light absorption, optimized active layer morphology, and improved charge transport and mobility. The study demonstrates the potential of combining fullerene and non-fullerene acceptors for high-performance OPDs.
研究不足
The study focuses on the effect of PC71BM addition on OPD performance but does not explore the long-term stability or scalability of the devices. The optimal PC71BM ratio was found to be 10 wt%, beyond which performance degraded due to increased aggregation and charge recombination.
1:Experimental Design and Method Selection:
The study involved the fabrication of OPDs with a structure of ITO/ZnO/P3HT:IEICO-4F:PC71BM/MoO3/Ag, where the ratio of PC71BM was varied to study its effect on device performance.
2:Sample Selection and Data Sources:
The materials used included P3HT, IEICO-4F, and PC71BM, purchased from Solarmer, and dissolved in chlorobenzene.
3:List of Experimental Equipment and Materials:
Equipment included a spectroscopy (Shimazu UV1700), a Hitachi F-7000 PL spectroscopy, a Keithley 4200 programmable voltage-current source, and AFM (Agilent, AFM 5000).
4:0). Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: The ZnO precursor was spin-coated on ITO substrates, followed by the spin-coating of the active layer solutions. The devices were then annealed and completed with the deposition of MoO3 and Ag layers.
5:Data Analysis Methods:
The performance of the OPDs was evaluated through J-V characteristics, EQE spectra, and charge carrier mobility measurements using the SCLC method.
独家科研数据包,助您复现前沿成果,加速创新突破
获取完整内容