研究目的
To improve the device efficiency and stability of carbon nanotube-based silicon solar cells through chemical doping, antireflection coating, and encapsulation.
研究成果
The application of polymeric acid (Nafion) to SWNT-based silicon solar cells significantly improves their power conversion efficiency and stability. The multifunctional effects of p-doping, antireflection, and encapsulation by Nafion lead to a stable efficiency of 14.4%, the highest reported for carbon nanotube-based silicon solar cells.
研究不足
The study focuses on the application of Nafion for improving the efficiency and stability of SWNT-based silicon solar cells. The limitations include the specific conditions under which the experiments were conducted and the potential for further optimization of the Nafion application process.
1:Experimental Design and Method Selection:
The study involved the application of a polymeric acid (Nafion) to single-walled carbon nanotube (SWNT)-based silicon solar cells to observe multifunctional effects of p-doping, antireflection, and encapsulation.
2:Sample Selection and Data Sources:
SWNT films were synthesized by an aerosol chemical vapor deposition method. The SWNT-Si solar cells were fabricated by dry-transferring the SWNT film onto an n-type Si contact window.
3:List of Experimental Equipment and Materials:
Equipment included a Shimadzu UV-3150 for optical reflectance and transmittance spectra, Agilent 4156C analyzer for J–V curves, and a solar simulator PEC-L01 for light source. Materials included Nafion perfluorinated resin solution and propan-2-ol (IPA) for dopant preparation.
4:Experimental Procedures and Operational Workflow:
The Nafion solution was spin-coated on the SWNT-Si solar cells at 7000 rpm for 60 s, followed by drying in ambient conditions.
5:Data Analysis Methods:
The performance of the solar cells was assessed in terms of antireflection, doping effect, and stability. Optical analysis, sheet resistance measurement, and photoelectron yield spectroscopy (PYS) were used to analyze the effects.
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