研究目的
To bridge the gap in assessing the transient plasmonic optical response triggered by ultrashort laser pulses by developing a complex-conjugate pole-residue pair (CCPRP) approach for FDTD simulation.
研究成果
The CCPRP-based FDTD method, combined with the 3TM, effectively models the ultrafast transient variation of the near-field intensity enhancement in and around a gold nanoparticle. The method's accuracy was validated, and it was shown to be suitable for investigating phenomena triggered by ultrashort laser pulses related to near-field enhancement in plasmonic nanostructures.
研究不足
The approach is limited to a 'slow' variation of the dielectric function with respect to the time scale of the field oscillation, suitable for perturbative modeling. The study also notes discrepancies between FDTD calculations and Mie theory, possibly due to the geometrical representation of the AuNP in simulations.
1:Experimental Design and Method Selection:
The study employs a CCPRP-based FDTD simulator to model the ultrafast transient near field inside and around a gold nanoparticle (AuNP) upon absorption of a subpicosecond laser pulse. The methodology includes validating the FDTD tool's accuracy and integrating a three-temperature model (3TM) for calculating the transient dielectric function of the AuNP.
2:Sample Selection and Data Sources:
The study focuses on a spherical gold nanoparticle (AuNP) of 20-nm diameter in air, illuminated by an ultrashort laser pulse with specific characteristics.
3:List of Experimental Equipment and Materials:
The computational setup includes a 3D-FDTD simulation with a gold layer and perfectly matched layers (PMLs) for absorbing residual waves.
4:Experimental Procedures and Operational Workflow:
The procedure involves calculating the transient dielectric function at each delay time using the 3TM, performing pole-residue decomposition, and simulating the electric field inside and around the NP using FDTD.
5:Data Analysis Methods:
The analysis includes comparing the simulated transient near-field intensity enhancement with results from Mie theory and examining its dependence on distance from the nanoparticle surface and delay time after laser pulse absorption.
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