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Optimization of Transparent Passivating Contact for Crystalline Silicon Solar Cells

DOI:10.1109/JPHOTOV.2019.2947131 期刊:IEEE Journal of Photovoltaics 出版年份:2019 更新时间:2025-09-11 14:15:04
摘要: A highly transparent front contact layer system for crystalline silicon (c-Si) solar cells is investigated and optimized. This contact system consists of a wet-chemically grown silicon tunnel oxide, a hydrogenated microcrystalline silicon carbide [SiO2/μc-SiC:H(n)] prepared by hot-wire chemical vapor deposition (HWCVD), and a sputter-deposited indium doped tin oxide. Because of the exclusive use of very high bandgap materials, this system is more transparent for the solar light than state of the art amorphous (a-Si:H) or polycrystalline silicon contacts. By investigating the electrical conductivity of the μc-SiC:H(n) and the influence of the hot-wire filament temperature on the contact properties, we find that the electrical conductivity of μc-SiC:H(n) can be increased by 12 orders of magnitude to a maximum of 0.9 S/cm due to an increased doping density and crystallite size. This optimization of the electrical conductivity leads to a strong decrease in contact resistivity. Applying this SiO2/μc-SiC:H(n) transparent passivating front side contact to crystalline solar cells with an a-Si:H/c-Si heterojunction back contact we achieve a maximum power conversion efficiency of 21.6% and a short-circuit current density of 39.6 mA/cm2. All devices show superior quantum efficiency in the short wavelength region compared to the reference cells with a-Si:H/c-Si heterojunction front contacts. Furthermore, these transparent passivating contacts operate without any post processing treatments, e.g., forming gas annealing or high-temperature recrystallization.
作者: Malte K?hler,Manuel Pomaska,Alexandr Zamchiy,Andreas Lambertz,Weiyuan Duan,Florian Lentz,Shenghao Li,Vladimir Smirnov,Thomas Kirchartz,Friedhelm Finger,Uwe Rau,Kaining Ding
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To investigate and optimize a highly transparent front contact layer system for crystalline silicon (c-Si) solar cells, focusing on improving electrical conductivity and reducing contact resistivity while maintaining high transparency.

The developed transparent passivating contact (TPC) for c-Si solar cells, consisting of SiO2/μc-SiC:H(n), shows superior transparency and electrical properties compared to traditional contacts. Optimizing the filament temperature during μc-SiC:H(n) deposition significantly improves electrical conductivity and reduces contact resistivity, leading to solar cells with a maximum power conversion efficiency of 21.6%. The TPC operates without post-processing treatments, offering a lean process flow.

The study is limited by the sensitivity of the passivation quality to the deposition conditions, particularly the filament temperature, which affects the electrical conductivity and contact resistivity. The exact mechanism for high passivation quality directly after deposition is still under investigation.

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