研究目的
To investigate and optimize a highly transparent front contact layer system for crystalline silicon (c-Si) solar cells, focusing on improving electrical conductivity and reducing contact resistivity while maintaining high transparency.
研究成果
The developed transparent passivating contact (TPC) for c-Si solar cells, consisting of SiO2/μc-SiC:H(n), shows superior transparency and electrical properties compared to traditional contacts. Optimizing the filament temperature during μc-SiC:H(n) deposition significantly improves electrical conductivity and reduces contact resistivity, leading to solar cells with a maximum power conversion efficiency of 21.6%. The TPC operates without post-processing treatments, offering a lean process flow.
研究不足
The study is limited by the sensitivity of the passivation quality to the deposition conditions, particularly the filament temperature, which affects the electrical conductivity and contact resistivity. The exact mechanism for high passivation quality directly after deposition is still under investigation.
1:Experimental Design and Method Selection:
The study focuses on optimizing a transparent passivating contact system for c-Si solar cells, using a combination of wet-chemical oxidation, HWCVD for μc-SiC:H(n) deposition, and sputter deposition for ITO layers.
2:Sample Selection and Data Sources:
Double side random pyramids textured 1 Ω·cm n-type Czochralsky silicon wafers were used. Material properties were studied on glass and <100> polished float-zone Si.
3:List of Experimental Equipment and Materials:
Equipment includes a hot-wire chemical vapor deposition system, sputter deposition system, Vecco dektak 6M Stylus Profiler, Sinton Instruments WCT-120 lifetime tester, and FTIR spectrometer. Materials include monomethylsilane, hydrogen, nitrogen, and indium doped tin oxide.
4:Experimental Procedures and Operational Workflow:
The process involves wafer cleaning, wet-chemical oxidation, μc-SiC:H(n) deposition by HWCVD at varying filament temperatures, passivation quality and contact resistivity measurements, and solar cell fabrication with TCO and silver metallization.
5:Data Analysis Methods:
Electrical conductivity was measured using coplanar silver pads, nitrogen concentration by ToF-SIMS, crystallite size by XRD and FTIR, and solar cell performance by IV parameters, quantum efficiency, and reflectance measurements.
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