研究目的
Investigating the use of strontium titanate (SrTiO3) as an electron transport layer to enhance the charge extraction and stability of perovskite solar cells.
研究成果
STO as an ETL in PSCs offers a promising route towards efficient and stable solar cells, with a PCE of 19% and improved stability under continuous illumination, retaining ~80% of initial efficiency after 1000 hours.
研究不足
The study focuses on n-i-p configuration PSCs and the stability tests are conducted under nitrogen atmosphere, which may not fully represent operational conditions in air.
1:Experimental Design and Method Selection:
The study employed a combustion synthesis approach for STO thin film fabrication, requiring only a 150 °C post-deposition annealing.
2:Sample Selection and Data Sources:
STO powder was synthesized via a low-temperature polymeric matrix approach.
3:List of Experimental Equipment and Materials:
Instruments included XRD, DSC, UV-Vis spectrometer, TEM, SEM, UPS, TR-PL, TPC, and TPV.
4:Experimental Procedures and Operational Workflow:
STO films were spin-coated on ITO substrates, followed by perovskite layer deposition, HTL application, and gold electrode evaporation.
5:Data Analysis Methods:
Performance metrics were analyzed using J-V characteristics, EQE spectra, and stability tests under continuous illumination.
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UV-Vis-NIR Spectrometer
Cary 7000
Agilent
Recording transmittance and absorbance spectra of the films
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Transmission Electron Microscope
Titan 80-300
FEI
Imaging the cross-sectional interface of samples
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Scanning Electron Microscope
Auriga
Zeiss
Collecting SEM micrographs
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Differential Scanning Calorimeter
Discovery DSC
TA
Investigation of the thermal behavior of SrTiO3
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Ultraviolet Photoelectron Spectroscopy
PHOIBOS 100
SPECS
Measuring the work function and valence band maximum
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