研究目的
Investigating the synthesis and application of a novel asymmetrical zinc(II) phthalocyanine-BODIPY conjugate in bulk heterojunction solar cells.
研究成果
The novel ZnPc-BODIPY conjugate showed panchromatic behavior and effective energy transfer from the BODIPY units to the phthalocyanine core. It was successfully used as a donor in bulk heterojunction solar cells, showing potential for improving photovoltaic parameters with increased concentration.
研究不足
The study is limited by the technical constraints of the synthesis and characterization methods used, as well as the potential for optimization in the solar cell fabrication process.
1：Experimental Design and Method Selection:
The synthesis of ZnPc-BODIPY conjugate involved the reaction of carboxylic acid substituted asymmetrical zinc(II) phthalocyanine (ZnPc) with BODIPY derivative bearing amino group (BODIPY-NH2). The conjugate was characterized by spectroscopic methods and elemental analysis.
2：2). The conjugate was characterized by spectroscopic methods and elemental analysis. Sample Selection and Data Sources:
2. Sample Selection and Data Sources: The compounds ZnPc, BODIPY-NH2, and ZnPc-BODIPY were synthesized and used for the study.
3：List of Experimental Equipment and Materials:
FT-IR, UV-Vis, 1H NMR, 11B NMR, 19F NMR, mass spectrometers, and elemental analysis instruments were used.
4：Experimental Procedures and Operational Workflow:
The synthesis, characterization, and fabrication of solar cells were performed step-by-step.
5：Data Analysis Methods:
The data were analyzed using spectroscopic, electrochemical, and theoretical methods.
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