研究目的
Investigating the effects of barium titanate (BTO) nanoparticles content and reaction temperature on the electro-optical properties of polymer-dispersed liquid crystal (PDLC) films prepared by nucleophile-initiated thiol-ene click reaction.
研究成果
Doping BTO nanoparticles into PDLC films prepared by nucleophile-initiated thiol-ene click reaction can optimize their electro-optical properties, with the optimal BTO content and reaction temperature identified. The study demonstrates the potential for improving PDLC film performance through nanoparticle doping and temperature control.
研究不足
The study is limited to the effects of BTO nanoparticles and reaction temperature on PDLC films. The influence of other nanoparticles or different preparation methods was not explored.
1:Experimental Design and Method Selection:
PDLC films doped with BTO nanoparticles were prepared using the nucleophile-initiated thiol-ene click reaction. The effects of BTO content and reaction temperature on the electro-optical properties were explored.
2:Sample Selection and Data Sources:
Samples were prepared with varying BTO content (0wt% to 0.5wt%) and at different reaction temperatures (40°C, 60°C, 80°C).
3:5wt%) and at different reaction temperatures (40°C, 60°C, 80°C). List of Experimental Equipment and Materials:
3. List of Experimental Equipment and Materials: Materials included polyethylene glycol diacrylate (PEGDA400), hexyl acrylate (HA), 4-dimethylaminopyridine (DMAP), barium titanate (BTO), pentaerythritol tetra(3-mercaptopropionate) (PETMP), and liquid crystal E7. Equipment included a UV 1810 PC spectrometer, polarised optical microscope (POM), and scanning electron microscopy (SEM).
4:Equipment included a UV 1810 PC spectrometer, polarised optical microscope (POM), and scanning electron microscopy (SEM). Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: The preparation involved mixing components, filling into PET cells, and curing at specified temperatures. Electro-optical properties were measured, and morphological analysis was conducted.
5:Data Analysis Methods:
The electro-optical properties were analyzed based on transmittance, threshold voltage (Vth), and saturation voltage (Vsat). Morphological analysis was performed using POM and SEM.
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Polarised optical microscope
Olympus Model BH-2
Olympus
Used to observe the optical state of PDLC films.
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Scanning electron microscopy
Apreo S Hi Voc
American FEI Company
Used to observe the morphologies of the polymer structure in PDLC films.
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Polyethylene glycol diacrylate
PEGDA400
Aladdin Industrial Inc.
Used as a monomer in the preparation of PDLC films.
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Hexyl acrylate
HA
Aladdin Industrial Inc.
Used as a monomer in the preparation of PDLC films.
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4-dimethylaminopyridine
DMAP
Aladdin Industrial Inc.
Used as a catalyst in the nucleophile-initiated thiol-ene click reaction.
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Barium titanate
BTO
Aladdin Industrial Inc.
Doped into PDLC films to study its effects on electro-optical properties.
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Pentaerythritol tetra(3-mercaptopropionate)
PETMP
Rhawn Chemical Technology Co., Ltd.
Used as a crosslinking agent in the preparation of PDLC films.
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Liquid crystal
E7
Yantai Xian Hua Chem-Tech. Co., Ltd.
Used as the liquid crystal component in PDLC films.
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UV 1810 PC spectrometer
UV 1810 PC
Used to measure the electro-optical properties of PDLC films.
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