研究目的
Investigating the enhancement of efficiency in PbS/CdS quantum dot-sensitized solar cells through the incorporation of plasmonic Ag nanoparticles.
研究成果
The incorporation of plasmonic Ag nanoparticles into TiO2 photoanodes sensitized with PbS/CdS quantum dots significantly enhances the efficiency of QDSSCs by improving optical absorption through localized surface plasmon resonance. This results in a 15% increase in overall efficiency and a 23% increase in short-circuit current density.
研究不足
The study focuses on the enhancement of efficiency through plasmonic Ag nanoparticles but does not explore the long-term stability or scalability of the fabricated QDSSCs.
1:Experimental Design and Method Selection:
The study involved the fabrication of plasmonic Ag colloidal nanoparticle-incorporated TiO2 double-layer electrodes sensitized with PbS/CdS core-shell quantum dots using the SILAR technique. QDSSCs were fabricated with polysulfide electrolyte and Cu2S counter electrode.
2:Sample Selection and Data Sources:
Fluorine-doped tin oxide (FTO)-coated glass, TiO2 P90 and P25 powders, and various chemicals for synthesis and fabrication were used.
3:List of Experimental Equipment and Materials:
ZEISS EVO Scanning Electron Microscope, JEOL JEM-2100 high-resolution transmission electron microscope (HRTEM), Shimadzu 2450 UV–Vis spectrophotometer, Keithley 2000 model multi-meter, Autolab potentiostat/galvanostat PGSTAT128 N.
4:Experimental Procedures and Operational Workflow:
Synthesis of Ag nanoparticles, preparation of TiO2 double-layered photoanode, incorporation of PbS/CdS quantum dots, preparation of the electrolyte and counter electrode, fabrication of QDSSC, and characterization.
5:Data Analysis Methods:
Optical absorption spectra, current–voltage characterization, and electrochemical impedance spectroscopy (EIS) were used to analyze the performance of the QDSSCs.
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