研究目的
Investigating the fabrication of high aspect ratio microstructures for silicon micropillar array solar cells using an enhanced metal assisted etching method.
研究成果
The study successfully demonstrated an improved MAE method for fabricating high aspect ratio micropillars with smooth sidewalls, achieving a maximum solar cell efficiency of 17.26%. The use of ethanol in the etching solution and increased HF concentration were key to reducing porosity and undesired lateral etching. Future improvements in surface passivation and metallisation could further enhance performance.
研究不足
The study notes that surface recombination and series resistance increase with micropillar length, limiting the efficiency for very long micropillars. Additionally, the backside of samples exposed to etching solution for longer durations may suffer from higher recombination rates.
1:Experimental Design and Method Selection:
The study employed photolithography and metal assisted etching (MAE) methods to fabricate highly ordered Si micropillars. The use of ethanol as a solvent and varying HF concentrations in the MAE solution were explored to improve surface quality.
2:Sample Selection and Data Sources:
p-type, double sided, polished Si (1 0 0) wafers with a resistivity of 1–10 Ω cm were used. The fabrication process included standard doping, SiO2/SiNx passivation, and metallisation steps.
3:List of Experimental Equipment and Materials:
Equipment included a SEMCO Engineering LYDOP (POCl3) furnace for phosphorus doping, a SEMCO Engineering Direct Plasma PECVD system for SiNx:H layer deposition, and a BTU International conveyor belt furnace for metal diffusion and sintering. Materials included HF, H2O2, ethanol, and gold film for the MAE process.
4:Experimental Procedures and Operational Workflow:
The process involved photolithography, gold film evaporation, MAE with varying solutions and durations, doping, passivation, and metallisation. The etching solutions were freshly prepared for each sample.
5:Data Analysis Methods:
Performance parameters of the solar cells, such as short circuit current density (Jsc), open circuit voltage (Voc), fill factor (FF), and efficiency, were analyzed under A.M. 1.5 G conditions using an AAA class solar simulator.
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