研究目的
Investigating the effect of using ink containing polyacrylate and silicone surfactant on the inkjet printing of quantum dot films to eliminate the coffee ring effect and achieve uniform films.
研究成果
A uniform QD film without a coffee ring structure was successfully printed by optimizing the polyacrylate content to 12 wt%, the silicone surfactant BD-3033H content to 0.10 wt%, and the substrate temperature to 40°C. This provides a technical guarantee for the fabrication of QD devices in the future.
研究不足
The study focused on optimizing the polyacrylate and silicone surfactant contents and the substrate temperature for inkjet printing of QD films. Other factors that might affect the film uniformity, such as the solvent composition and printing environment, were not extensively explored.
1:Experimental Design and Method Selection:
The study involved preparing stable and well-dispersed ink by adding polyacrylate and silicone surfactant BD-3033H to ink, then optimizing the contents of these additives and the substrate temperature to achieve uniform quantum dot (QD) films.
2:Sample Selection and Data Sources:
Red-QD CdSe@ZnS liquid was used as the QD material, dissolved in a mixed solvent of toluene and o-dichlorobenzene.
3:List of Experimental Equipment and Materials:
A MicroFab JETLAB II piezoelectric printer equipped with a 30-μm-diameter nozzle was used for inkjet printing. Viscosity and surface tension measurements were carried out using a viscometer and an automatic surface tension meter, respectively.
4:Experimental Procedures and Operational Workflow:
The ink was prepared by dissolving QDs in a mixed solvent, adding polyacrylate and BD-3033H, then ultrasonically oscillating the mixture. The printing parameters were optimized to eliminate satellite droplets.
5:Data Analysis Methods:
The morphology of the QD films was observed with an optical microscope and a 3D microscope, and the thicknesses were measured using a step profiler.
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MicroFab JETLAB II piezoelectric printer
JETLAB II
MicroFab
Used for inkjet printing of QD films
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Optical microscope
BX51M
Olympus
Used to observe the 2D morphologies of the QD films
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3D microscope
OLS4100
Olympus
Used to investigate the 3D morphologies of the QD films
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Step profiler
Dektak-XT
Bruker
Used to measure the thicknesses of the QD films
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Red-QD CdSe@ZnS liquid
Tianjin Xingguang Yinghua Co., Ltd
Used as the quantum dot material in the ink
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Toluene
Sinopharm Chemical Reagent Co., Ltd
Used as a solvent in the ink preparation
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O-dichlorobenzene
oDCB
Shanghai Macklin Biochemical Co., Ltd
Used as a solvent in the ink preparation
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Silicone surfactant
BD-3033H
Hangzhou Bald Advanced Materials Co., Ltd
Added to the ink to improve film uniformity
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Polyacrylate
Guangdong Poly Optoelectronics Co., Ltd
Added to the ink to hinder the outward flow of QDs
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PC substrates
Dongguan Qiyi Plastic Material Co., Ltd
Used as the substrate for inkjet printing
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Viscometer
DV2T
Brookfield
Used to measure the viscosity of the inks
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Automatic surface tension meter
BZY-1
Hengping
Used to measure the surface tension of the inks
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