研究目的
Investigating the effect of tantalum doping on SnO2 electron transport layer for perovskite solar cells to improve conductivity and transmittance without declining the light transmittance property.
研究成果
Ta-doped SnO2 as an ETL significantly improves the performance of PSCs by enhancing conductivity and transmittance, facilitating electron extraction, and reducing recombination at the interface. The optimal doping ratio of Ta/Sn is found to be 1.0 mol. %, achieving a champion device PCE of 20.80%.
研究不足
The study is limited by the doping ratio's effect on the crystal structure and interface contact with the perovskite layer, where excessive doping may lead to poorer interface contact and increased defects.
1:Experimental Design and Method Selection:
The study employs chemical bath deposition (CBD) to grow Ta-doped SnO2 (Ta-SnO2) as an ETL for low-temperature PSCs.
2:Sample Selection and Data Sources:
Samples include undoped SnO2 and Ta-SnO2 films with different Ta contents.
3:List of Experimental Equipment and Materials:
Instruments used include scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS).
4:Experimental Procedures and Operational Workflow:
The process involves the preparation of SnO2 and Ta-SnO2 films, characterization of their morphological and optoelectronic properties, and fabrication of PSC devices.
5:Data Analysis Methods:
The study analyzes the conductivity, transmittance, and performance parameters of PSCs based on the prepared ETLs.
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