研究目的
Investigating the degradation of fragmented microplastics, particularly low-density polyethylene (LDPE) film in water, through visible light-induced plasmonic photocatalysts comprising platinum nanoparticles deposited on zinc oxide (ZnO) nanorods (ZnO-Pt).
研究成果
The plasmonic photocatalyst (ZnO-Pt) showed enhanced visible light absorption and reduced electron-hole recombination, leading to improved photocatalytic performance. The study demonstrated effective degradation of LDPE films, suggesting a viable method for mitigating microplastic pollution using sunlight.
研究不足
The study focuses on the degradation of LDPE films and may not be directly applicable to other types of microplastics. The photocatalytic efficiency under natural sunlight conditions was not extensively studied.
1:Experimental Design and Method Selection:
The study involved the synthesis of ZnO nanorods by a hydrothermal process and the deposition of platinum nanoparticles on ZnO nanorods using UV-C photoreduction method. The photocatalytic performance was evaluated by degrading methylene blue (MB) dye solution and LDPE film under visible light irradiation.
2:Sample Selection and Data Sources:
LDPE film with a thickness of 50 microns was used for photocatalytic degradation studies. Methylene blue dye was used as a model organic contaminant.
3:List of Experimental Equipment and Materials:
Zinc acetate dihydrate, hexamethylenetetramine, zinc nitrate hexahydrate, and potassium hexachloroplatinate were used. A 50 W dichroic halogen lamp was used for visible light illumination.
4:Experimental Procedures and Operational Workflow:
The photocatalytic activity was tested by following the degradation of MB dye solution and LDPE film under visible light irradiation. The changes in carbonyl and vinyl indices were monitored using FTIR spectroscopy.
5:Data Analysis Methods:
The degradation kinetics were analyzed using UV-VIS spectrophotometry. The morphological changes were examined by SEM, and the crystal structure was analyzed by HR-TEM.
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HR-TEM
JEOL JEM-2100F
JEOL
Used for observing morphology and crystal structure of platinum nanoparticle-coated ZnO nanorods
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UV-VIS spectrophotometer
LAMBDA-750
PerkinElmer
Used for determining optical absorbance of catalysts and degradation kinetics of MB dye
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Photoluminescence spectrophotometer
LS 55
PerkinElmer
Used for assessment of intrinsic and UV-induced defect density for ZnO and ZnO-Pt samples
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FTIR spectrometer
Nicolet? iS10
Thermo Fisher Scientific
Used for obtaining FTIR spectra of LDPE film to observe variations of functional groups during photocatalytic degradation
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SEM
GEMINI Ultra 55
ZEISS
Used for examining surface topography and morphology of catalysts and LDPE
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zinc acetate dihydrate
Sigma-Aldrich Chemie GmbH
Used in the synthesis of ZnO nanorods
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hexamethylenetetramine
Sigma-Aldrich Chemie GmbH
Used in the synthesis of ZnO nanorods
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zinc nitrate hexahydrate
Sigma-Aldrich Chemie GmbH
Used in the synthesis of ZnO nanorods
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potassium hexachloroplatinate
Sigma-Aldrich Chemie GmbH
Used in the deposition of platinum nanoparticles on ZnO nanorods
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LDPE film
Used as a model microplastic pollutant for photocatalytic degradation studies
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dichroic halogen lamp
50 W
Used for visible light illumination in photocatalytic degradation studies
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