摘要： This paper reported a facile synthesis path to realize high-luminescent rare-earth-free composite powder, by embedding blue/green-emitting N-doped carbon dots into silica nano-spheres (CD@SiO2). Carbon dots were evenly dispersed in CD@SiO2 composites and eventually the aggregation-induced luminescence quenching is eliminated. Compared to the naked CDs, CD@SiO2 composites exhibit perfectly spherical morphology with average size of ~200 nm, signi?cantly enhanced emission intensity (> 4 times) and better thermal stability (T50 > 150 °C). As-synthesized CD@SiO2 own strong blue/green emission with high quantum e?ciency (QE) over 60%. White LEDs prototypes with promising properties, i.e. CRI = 89.1, CCT = 4850 K and CIE coordinates = (0.3514, 0.3715), were fabricated by combining blue/green CD@SiO2 and red CdTe@CaCO3 composites with NUV chip. All results indicate that these rare-earth-free, mono-dispersed spherical, and thermal-stable composite materials with e?cient blue/green emission could be an exceptional choice as phosphors for LED application.