摘要： Organic ligands capped on surface of perovskite nanocrystals (PeNCs) strongly influence the optical and electrical properties of the obtained PeNCs films, which are fundamental for efficient perovskite light-emitting diodes (PeLEDs). Here, we investigate the ligands effect through introduction of ligands with strong π conjugation, 1-(1-naphthyl)ethylamine bromide (NEABr), for the fabrication of FAPbBr3 PeNCs. Compared to the widely applied ligands of phenylethylamine bromide (PEABr), NEABr molecules containing naphthalene ring possess more delocalized electrons and better conductivity, which is beneficial for charge injection and transportation between interfaces. By varying the ligands ratio, high quality three dimensional FAPbBr3 PeNCs films with photoluminescence quantum yields up to 80% are fabricated. Based on the optimized PeNCs films, electroluminescent (EL) devices achieve a maximum external quantum efficiency of 8.6%, which is about three times higher than that of EL devices based on PEABr. Importantly, through understanding into the ligands effect, we demonstrate that the enhanced device efficiency is attributed to lower defect densities and decreased interfacial resistance in NEABr derived EL devices. Our findings about ligands conjugation on device performance may benefit other perovskites based optoelectronic devices.