摘要： Carrier mobility is a critical factor for power conversion efficiency (PCE) of polymer solar cells (PSCs), and the low charge carrier mobility still limits performance improvement of PSCs. Adding high mobility material into the active layer is one of the better ways to enhance the PCE of PSCs. Two-dimensional (2D) Bi2O2Se can be an ideal additive material for improving the carrier mobility of PSCs because its ultrahigh mobility and high thermal stability. In this work, the Bi2O2Se few-layer 2D nanoflakes are fabricated by combining lithium intercalation with shear force-assisted liquid phase exfoliation and applied as an additive to promote charge transport in PSCs for the first time. The 2D Bi2O2Se nanoflakes, when introduced into the active layer, not only provide new interface between donor and acceptor and efficient charge transfer pathways but also induce crystallization of photosensitive layer and form the continuous interpenetrating networks, which promotes the exciton separation and charge transfer in photosensitive layer. As a result, the PCE of device based on PBDB-T:ITIC is increased from 10.09% (0 wt%) to 12.22% (2 wt%). Meanwhile, the PCE of device based on PM6:Y6 is also increased from 14.59% for binary device to 16.28% for optimized ternary device (2 wt%). Moreover, the optimized ternary device shows excellent air stability by suppressing the mixing of the two phases. This work supplies a good method to enhance the PCE of PSCs, also shows the Bi2O2Se material has a good prospect in photovoltaic devices.