摘要： Two-dimensional (2D) transition metal carbides MXene, typically represented by Ti3C2TX, have shown great promise in optoelectronic devices due to their metallic electrical conductivity, large surface area, superior hydrophilicity and excellent transparency. Herein, to improve the conductivity of polymer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) film, we incorporate solution-processable 2D Ti3C2Tx nanosheets into PEDOT:PSS to fabricate PEDOT:PSS/Ti3C2TX composite layers, and polymer solar cells (PSCs) with PEDOT:PSS/Ti3C2TX composite films as hole transport layers (HTLs) are fabricated for the first time. The nanostructures and the corresponding hole injection properties of PEDOT:PSS/Ti3C2TX composite layers are systematically evaluated. Based on the non-fullerene PBDB-T:ITIC system, a power conversion efficiency (PCE) of 11.02% is obtained for the device with PEDOT:PSS/Ti3C2TX as HTL, which is improved by 13.5% than that of the control device with pure PEDOT:PSS as HTL (9.72%). When using the PM6:Y6 system as the active layer, the PCE of the device based on PEDOT:PSS/Ti3C2TX is improved to 14.55% from 13.10% for the PEDOT:PSS reference device. 2D Ti3C2TX nanoflakes with higher conductivity constructing additional charge transfer pathways between the PEDOT nanocrystals and inducing conformational transition of PEDOT from a coil to a liner/expanded-coil structure, leading to the conductivity and device performance improvement. Interestingly, PEDOT:PSS/Ti3C2TX based devices also exhibit enhanced long-term stability than PEDOT:PSS based device. These results show that PEDOT:PSS/Ti3C2TX composite film has a promising prospect in high efficiency organic optoelectronics.