研究目的
Investigating the use of zirconia (ZrO2) quantum dots (QDs) for the formation of an active layer in nonvolatile resistive random access memory devices to achieve high performance and stability.
研究成果
The Ag/ZrO2/Ti devices exhibit a high resistance state/low resistance state resistance difference, good cycle performance, and a relatively low conversion current. The study demonstrates the potential of ZrO2 QDs as an active layer in high-performance memory devices through a simple spin-coating method.
研究不足
The preparation methods for RRAM devices are complex, usually involving magnetron sputtering. The study aims to simplify this with a spin-coating method but may face challenges in scalability and uniformity.
1:Experimental Design and Method Selection:
The study employs a facile spin-coating method to fabricate memory devices with a sandwich structure of Ag/ZrO2/Ti.
2:Sample Selection and Data Sources:
Aqueous nanodispersion of ZrO2 QDs is synthesized using a hydrothermal method coupled with an alkaline hydrogen peroxide (AHP) process.
3:List of Experimental Equipment and Materials:
Includes a spin coater (KW-4A), SEM (Hitachi S4800), AFM (Bruker Dimension Icon), TEM (Hitachi HT-7700), HRTEM (Hitachi H-9500), XRD-6000 diffractometer (Shimadzu Inc.), and CHI 660B electrochemical workstation (CH Instruments).
4:Experimental Procedures and Operational Workflow:
The ZrO2 QDs are spin-coated onto titanium foils, dried, and then Ag is sputtered on top to form the sandwich structure.
5:Data Analysis Methods:
The performance of the memory devices is analyzed through I-V curves, and the conductive mechanism is studied focusing on Ag ions and oxygen vacancies.
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SEM
Hitachi S4800
Hitachi
Used to examine the density of the stacked layers and coating morphology of the ZrO2/Ti foil.
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AFM
Bruker Dimension Icon
Bruker
Used to investigate the surface morphology of the ZrO2/Ti foil.
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TEM
Hitachi HT-7700
Hitachi
Used to obtain the magnitude and morphology of the ZrO2 nanoparticles.
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HRTEM
Hitachi H-9500
Hitachi
Used to determine the lattice structure and size of the ZrO2 QDs.
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XRD diffractometer
XRD-6000
Shimadzu
Used to measure the XRD patterns of the samples.
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electrochemical workstation
CHI 660B
CH Instruments
Used to measure the current-voltage (I-V) curves of the Ag/ZrO2/Ti devices.
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spin coater
KW-4A
Used for spin-coating the ZrO2 QDs onto titanium foils.
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