研究目的
The primary objective of this study is to determine whether the carbon quantum dots can act as an electron donor and can participate in the different photo physical processes.
研究成果
This work demonstrates that CQDLs can be used as a donor species for different photo physical processes such as photovoltaic cell, Dye sensitized solar cell, and also for antioxidant activity study. The quenching of CQDs by MG is due to fluorescence resonance energy transfer with a donor acceptor distance of 5.33 nm.
研究不足
The exact mechanism of formation of CQDs from lotus precursor is yet unknown. The study is limited to the interaction between CQDLs and MG under ambient pH condition (pH 7).
1:Experimental Design and Method Selection:
Carbon quantum dots (CQDLs) are synthesized using a simple carbonization method with petals of Nelumbo nucifera L. as a carbon precursor. The interaction between CQDLs and malachite green (MG) is studied using fluorescence spectroscopic techniques.
2:Sample Selection and Data Sources:
Lotus petals were collected from the open market of Purba Bardhaman, West Bengal, India. Malachite green was purchased from Merck-India.
3:List of Experimental Equipment and Materials:
UV-VIS 2450 spectrophotometer, Hitachi F-7000 spectrofluorimeter, High Resolution Transmission Electron Microscope (HRTEM, JEOL JEM 2100), FT-IR spectrophotometer (Shimadzu FTIR model IR Prestige 21 CE), time-correlated single photon counting (TCSPC) method on a FluoroCube-01-NL spectrometer.
4:Experimental Procedures and Operational Workflow:
The synthesized CQDLs were characterized by UV?Vis absorption, FT-IR, TEM, steady-state and time-resolved fluorescence spectroscopy. The quenching mechanism of CQDLs with MG was investigated using Stern-Volmer equation and time-resolved fluorescence lifetime studies.
5:Data Analysis Methods:
The fluorescence quantum yield (QY) of CQDs was measured using coumarin 480 (C480) as a reference. The quenching process was analyzed using the Stern-Volmer plot and the modified Stern-Volmer equation.
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UV-VIS 2450 spectrophotometer
2450
Shimadzu
Recording the absorption spectra of CQDs in the aqueous medium.
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Hitachi F-7000 spectrofluorimeter
F-7000
Hitachi
Recording the steady state emission and excitation spectra.
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High Resolution Transmission Electron Microscope
JEM 2100
JEOL
Characterizing the size and shape of the CQDLs.
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FT-IR spectrophotometer
IR Prestige 21 CE
Shimadzu
Recording Fourier transform infrared (FT-IR) spectra.
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FluoroCube-01-NL spectrometer
FluoroCube-01-NL
Carrying out time-resolved fluorescence decay measurements.
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laser diode
DD-450L-8666
Light source for excitation of the samples at λex = 375 nm.
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