研究目的
Investigating the use of solution-processed polymeric thin film as a transparent electrode for flexible perovskite solar cells to address the challenges of rigidity, frangibility, and high cost associated with traditional ITO or FTO coated glass substrates.
研究成果
The study demonstrates a simple yet effective method to fabricate flexible perovskite solar cells using a solution-processed polymeric thin film as the transparent electrode. Despite lower efficiencies compared to rigid electrodes, the approach offers a promising route for developing flexible PSCs.
研究不足
The study identifies poor electrical conductivity of the solution-processed transparent polymeric electrode and serious interfacial charge carrier recombination as the main limitations, leading to lower power conversion efficiencies compared to traditional ITO/glass substrates.
1:Experimental Design and Method Selection
The study involves the fabrication of perovskite solar cells (PSCs) using a solution-processed polymeric thin film as the transparent electrode. The methodology includes the treatment of PEDOT:PSS thin films with formamidinium iodide (FAI) to enhance electrical conductivity and optical transparency.
2:Sample Selection and Data Sources
PEDOT:PSS (Clevios PH1000) was used as the polymeric thin film. Perovskite solar cells were fabricated on both glass and flexible polyethylene terephthalate (PET) substrates.
3:List of Experimental Equipment and Materials
Materials include PEDOT:PSS (Clevios PH1000), PC61BM, PbI2, PTAA, DMF, IPA, ethyl alcohol, CB, FAI, and MAI. Equipment includes a profilometer, UV-Vis-NIR spectrophotometer, SEM, and solar simulator.
4:Experimental Procedures and Operational Workflow
PEDOT:PSS solution was spin-coated on substrates, treated with FAI, and thermally annealed. PSCs were fabricated with a device configuration of PET (or glass)/FAI-treated PEDOT:PSS/PTAA/CH3NH3PbI3/PC61BM/Al.
5:Data Analysis Methods
Device performance was characterized using J-V characteristics, EQE spectra, and impedance spectroscopy. Data analysis included the calculation of PCE, JSC, VOC, FF, and the analysis of charge carrier recombination.
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