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0D/2D plasmonic Cu2-xS/g-C3N4 nanosheets harnessing UV-vis-NIR broad spectrum for photocatalytic degradation of antibiotic pollutant

DOI:10.1016/j.apcatb.2019.118326 期刊:Applied Catalysis B: Environmental 出版年份:2019 更新时间:2025-09-19 17:13:59
摘要: Localized surface plasmon resonances (LSPRs) are usually achieved by some small grains of noble metal (Au, Ag et al.) to enhances the light absorption and charge carrier’s concentration of photocatalysts, but the wide application of noble metals is limited by their high cost. Here, we report the preparation of 0D/2D plasmonic Cu2-xS/g-C3N4 nanosheets (CSCNNs) and the utilization of LSPRs generated from Cu2-xS nanodots instead of noble metals to improve the photocatalytic activity for degradation of typical antibiotic levofloxacin (LVX). One-step hydrothermal method was employed to grow the highly effective in increasing the light absorption in near infrared (NIR) region and the theoretical analysis of band structure reveals the efficient separation and transmission mechanism of verify the strong light absorption capacity and longer carriers’ lifetime for CSCNNs. The dispersed Cu2-xS nanodots on the g-C3N4 nanosheets. Various characterization techniques region. Consequently, efficient photocatalytic degradation of LVX under full solar photogenerated electrons and holes. More importantly, LSPRs has been proved to be finite difference time domain (FDTD) simulations demonstrated that Cu2-xS LSPR-induced electromagnetic field in g-C3N4 nanosheets was far stronger than that of Ag and Au in NIR efficient LSPR photocatalysis system for treatment of antibiotic wastewater or other spectrum (UV-vis-NIR) can be achieved for CSCNNs. This work will lead to a cheap and photocatalytic applications.
作者: Liang Zhou,Zhihang Liu,Zhipeng Guan,Baozhu Tian,Lingzhi Wang,Yi Zhou,Yanbo Zhou,Juying Lei,Jinlong Zhang,Yongdi Liu
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Investigating the therapeutic effects of a specific herbal medicine on a particular disease.

The 0D plasmonic Cu2-xS nanodots were deposited on 2D g-C3N4 nanosheets successfully by a hydrothermal growth method. The obtained CSCNNs catalysts exhibited excellent electrical conductivity and favourable chemical stability. More prominent is the UV-vis-NIR broad spectrum. The absorption edge of the catalyst has been greatly expanded by the LSPR effect of appropriate Cu2-xS loading, the migration of charge carriers and the separation of electrons and holes were also promoted simultaneously.

The technical and application constraints of the experiments, as well as potential areas for optimization.

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