研究目的
Investigating the efficiency and color tunability of all-flexible microcavity semitransparent polymer solar cells (STPSCs) using polymer flexible one-dimensional photonic crystals (F-1DPCs) and ITO-free transparent electrodes in both fullerene- and nonfullerene-based systems.
研究成果
The study demonstrates that polymer F-1DPCs can significantly improve the efficiency of all-flexible STPSCs by enhancing photon absorption. The color tunability of these devices, especially in nonfullerene systems, offers potential for diverse applications. The findings provide a foundation for future research on optimizing STPSC performance and color characteristics for specific needs.
研究不足
The study is limited by the precision in controlling the film thickness uniformity of each layer in the multilayer films during the fabrication process. Additionally, the comparison between fullerene and nonfullerene systems is based on specific materials (J71:ITIC and PTB7:PCBM[70]), which may not generalize to all material combinations.
1:Experimental Design and Method Selection:
The study compares the performance of fullerene- and nonfullerene-based STPSCs with and without polymer F-1DPCs. The devices are fabricated using a combination of polymer F-1DPCs, UV/ozone plasma-treated polymer/ultrathin metal, and PEDOT:PSS transparent electrodes.
2:Sample Selection and Data Sources:
The nonfullerene photoactive layer is based on J71 as the donor and ITIC as the acceptor, while the fullerene-based photoactive layers use PTB7 as the donor and PCBM[70] as the acceptor.
3:List of Experimental Equipment and Materials:
Materials include J71, ITIC, PTB7, PCBM[70], PEDOT:PSS (Clevios PH1000), PFN, PMMA, PS, and ZnO. Equipment includes a Shimadzu UV-2550 UV-visible spectrophotometer, SEM (ULTRA55, Zeiss), Keithley 2400 source meter, and a Sun 2000 Solar Simulator.
4:Experimental Procedures and Operational Workflow:
Devices are fabricated on PET substrates with layers spin-coated or thermally evaporated under specific conditions. The performance is measured under AM
5:5G illumination. Data Analysis Methods:
Optical calculations are based on transfer matrix modelling, and device performance is analyzed using J-V characteristics and EQE measurements.
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