研究目的
To report the design, fabrication, and experimental characterization of dense, monolithic, and planar arrays of externally-fed electrospray emitters with an integrated extractor grid and carbon nanotube ?ow control structures for low-voltage and high-throughput electrospray of the ionic liquid EMI-BF4 in vacuum.
研究成果
The study demonstrates the first MEMS multiplexed electrospray source with an integrated extractor grid and CNT flow control structures for low-voltage high-throughput electrospray ion emission from ionic liquids in vacuum. The results show symmetric emission in both polarities with as much as 5 μA per emitter tip, start-up voltages as low as 470 V, and transmission as high as 80% through the extractor grid. The emission is uniform across the emitter arrays, and mass spectrometry confirms that emission occurs in the ionic regime.
研究不足
The current design of the electrospray source serves as a model to study emission from surface-fed emitters with porous coatings and is not yet intended for long-term operation. Without a continual liquid feed, the electrospray source can only be run for relatively short periods of time before the liquid is depleted.
1:Experimental Design and Method Selection:
The study involves the design and fabrication of dense, monolithic, and planar arrays of externally-fed electrospray emitters with an integrated extractor grid and carbon nanotube flow control structures. The methodology includes microfabrication techniques and experimental characterization of the arrays.
2:Sample Selection and Data Sources:
Microfabricated arrays with as many as 1900 emitters in 1 cm2 were fabricated and tested. The ionic liquid EMI-BF4 was used for electrospray in vacuum.
3:List of Experimental Equipment and Materials:
The equipment includes a commercial quadrupole mass spectrometer for mass spectrometry characterization, Keithley 2657A source-measure unit (SMU), and Keithley 6485 picoammeter for electrical characterization. Materials include silicon wafers, carbon nanotubes, and the ionic liquid EMI-BF
4:Experimental Procedures and Operational Workflow:
The process involves the fabrication of emitter and extractor grid dies, assembly of the device, and testing in vacuum. Electrical characterization is conducted using a triode configuration, and mass spectrometry is used to analyze the electrospray beam.
5:Data Analysis Methods:
The data analysis includes current-voltage characteristics, mass spectrometry analysis, and collector imprints to study deposition patterns and array emission uniformity.
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