摘要： P3HT-segment-based block copolymers have been reported to deliver an effective compatibilizer function in the P3HT:PC61BM bulk-heterojunction (BHJ) system to simultaneously improve performance and stability. However, as limited by the deficient optophysic properties of the P3HT:PC61BM system, the resultant power conversion efficiency (PCE) of compatibilizer-mediated devices is low despite the optimized chemical structures of the P3HT-segment-based block copolymers. To better shed light on such compatibilizer effect, the compatibilizer function of the P3HT-segment-based block copolymers is herein investigated in the emerging non-fullerene acceptor (NFA)-based BHJ systems. A P3HT analogue, poly[(4,4′-bis(2-butyloctoxycarbonyl-[2,2′-bithiophene]-5,5-diyl)-alt-(2,2′-bithiophene-5,5′-diyl)] (PDCBT), is used as the polymer donor since it shares the same backbone as P3HT to afford good compatibility with the P3HT-segment-based block copolymers and it has been proven to deliver a higher PCE than P3HT in the NFA BHJ systems. The P3HT-segment-based block copolymers (P1-P4) are manifested to offer similar compatibilizer function for the PDCBT-based NFA BHJ systems and the importance of their structural design is also revealed. As a result, addition of P4 delivers the largest enhancement in PCE: from 5.30% to 7.11% for the PDCBT:ITIC blend and from 6.21% to 8.04% for the PDCBT:IT-M blend. Moreover, it can also enhance device’s thermal stability, which can maintain 77% of initial PCE after annealing at 85 oC for 120 h (for the PDCBT:ITIC blend), outperforming the pristine binary device (66% preservation). More importantly, all the compatibilizer-mediated device exhibits an improved Voc. Such reduced potential loss can be attributed to the improved interfacial compatibility between the photoactive components, the most important function of a compatibilizer.