摘要： Surface plasmon-coupled emission (SPCE) has emerged as an interdisciplinary, versatile sensing platform due to its highly directional, solid-state and polarized emission. Here, we report the distinct properties rendered by Ag-Soret Colloids (Ag-SCs) such as nanovoids and nanocavities to observe 104-fold enhancement in emission intensity of omnidirectionally radiating emitter dipoles. Unlike earlier reports utilizing templated Ag-nanoparticles in spacer or cavity architectures, here we employ template-free, linker-less Ag-SCs. Purcell factor (PF - maximum of 120.6) obtained using the finite-difference time-domain (FDTD) simulations for soret nanocavities are in excellent agreement with the trend in emission enhancements obtained experimentally. Thermal gradient created by adiabatic cooling of Ag nanoparticles (AgNPs) drives their thermo-diffusion resulting in monodisperse nanoparticle assemblies (Ag-SCs). In addition, we report an extended-cavity architecture with Ag-SCs, as a novel pseudo-metal-dielectric-metal (p-MDM) interface, for achieving 80-fold SPCE. This study also features the unique properties of Ag-SCs as interfacial nanomaterials in SPCE platform to achieve femtomolar detection of glutathione (GSH). The quenching of fluorescence from alizarin red S-boric acid (ARS-BA) complex upon addition of Cu2+ ions and the dequenching upon GSH addition studied with Ag-SCs as spacer layer remarkably increased the sensitivity of the analyte. The uniform and intense electromagnetic field-confinement provided by these intricate architectures and hybrid interfaces, along with its ease of fabrication and versatility for variety of analytes, is critical to achieve augmented SPCE. This is accomplished without compromising on the reliability of detection as demonstrated with the use of a cellphone camera, CIE color space and luminosity plots for the turn-on fluorescence. The emission images were acquired using an android phone camera by aligning it with its angular emission, making it amenable for point-of-care diagnostics.