研究目的
To assess the stability of carbon-based perovskite solar cells (C-PSCs) under various conditions through an inter-laboratory study involving multiple testing protocols.
研究成果
The study demonstrates the remarkable stability of C-PSCs in the dark and under outdoor conditions, with over 1000 hours of stability reported. However, performance under continuous illumination is highly dependent on the load and lamp spectrum, with open circuit conditions being particularly severe. The findings suggest that real-world conditions, including light/dark cycles, are beneficial for long-term operation and should be included in stability studies.
研究不足
The study highlights the limitations of open circuit conditions for stability assessment and the impact of the carbon electrode's high series resistance on performance. The variability in testing conditions across laboratories may also introduce inconsistencies.
1:Experimental Design and Method Selection:
The study involved preparing carbon-based PSCs by screen printing, encapsulating them, and sending them to different laboratories across Europe for stability assessment under three ISOS aging protocols: dark (ISOS-D), simulated sunlight (ISOS-L), and outdoors (ISOS-O).
2:Sample Selection and Data Sources:
Samples were prepared at a single manufacturing site, encapsulated, and then distributed to five laboratories in four countries for testing.
3:List of Experimental Equipment and Materials:
Equipment included a Rofin Nd:YVO4 laser for etching, a spray pyrolysis setup for TiO2 layer deposition, screen printing for mesoporous layers, and encapsulation materials.
4:Experimental Procedures and Operational Workflow:
Devices were tested under controlled conditions according to ISOS protocols, with performance parameters monitored over time.
5:Data Analysis Methods:
Performance parameters were analyzed over time, with additional characterization techniques like Raman spectroscopy used to probe degradation products.
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