研究目的
To boost the efficiency and curtail the efficiency roll-off in green perovskite light-emitting diodes via incorporating ytterbium as cathode interface layer.
研究成果
The study demonstrates the potential of Yb as an efficient cathode interface layer for green PeLEDs, achieving high efficiency with low efficiency roll-off. The barrier-free, efficient electron injection enabled by the low work function of Yb is key to the improved performance.
研究不足
The study focuses on green PeLEDs and the efficiency roll-off issue is more severe in green and blue devices compared to red/infra-red counterparts. The exact origin of efficiency roll-off remains controversial.
1:Experimental Design and Method Selection:
The study employed a new device configuration of ITO/TFB/FA-based Quasi-2D Perovskite/TPBi/Yb/Ag to achieve high efficiency with low efficiency roll-off.
2:Sample Selection and Data Sources:
FA-based Quasi-2D perovskite with a composition of PEA2(FAPbBr3)n-1PbBr4 and Cs-based Quasi-2D perovskite as the emissive layers were used.
3:List of Experimental Equipment and Materials:
Materials included PbBr2, FABr, PEABr, CsBr, TFB, TPBi, Yb, Mg, Liq, Ag, and Al. Equipment included a thermal evaporator and a spectrophotometer.
4:Experimental Procedures and Operational Workflow:
The PeLEDs were fabricated by spin-coating the perovskite layer on ITO substrates, followed by thermal evaporation of the ETL, CIL, and cathode.
5:Data Analysis Methods:
The J-V-L characteristics were evaluated using a BM7A spectrophotometer and a Keithley 2400 source meter.
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ITO
Substrate for PeLEDs
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TFB
Xi’an Polymer Light Technology Corporation
Hole-transport layer
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TPBi
Xi’an Polymer Light Technology Corporation
Electron transport layer
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Yb
Cathode interface layer
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Ag
Cathode
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Al
Cathode
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Mg
Cathode interface layer
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Liq
Cathode interface layer
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