研究目的
To solve the problems of large surface roughness, chemical reaction between Ag and perovskite precursor, and migration of Ag in flexible perovskite solar cells by developing a composite electrode combining spray coated Ag nanowires and low-temperature sol-gel zinc oxide.
研究成果
The introduction of a low-temperature sol-gel ZnO layer on Ag NWs electrodes significantly improved the performance and stability of flexible perovskite solar cells by reducing surface roughness, preventing Ag migration, and enhancing mechanical and chemical stability. The optimized device achieved a power conversion efficiency of 13.12%, demonstrating the effectiveness of the composite electrode approach.
研究不足
The study focused on the suppression of Ag migration and improvement of device performance and stability but did not explore the long-term environmental stability under various conditions beyond continuous illumination in N2 filled glovebox.
1:Experimental Design and Method Selection:
The study involved the development of a composite electrode combining spray-coated Ag nanowires and low-temperature sol-gel zinc oxide to address issues in flexible perovskite solar cells. The methodology included optimizing the concentration and annealing temperature of sol-gel ZnO.
2:Sample Selection and Data Sources:
Silver nanowires dispersed in deionized water and diluted to 1.4 mg/mL with isopropanol (IPA) were used. The diameter and length of Ag nanowire are 30 nm and 20–30 μm, respectively.
3:4 mg/mL with isopropanol (IPA) were used. The diameter and length of Ag nanowire are 30 nm and 20–30 μm, respectively. List of Experimental Equipment and Materials:
3. List of Experimental Equipment and Materials: Materials included silver nanowires, zinc acetate, dimethoxy ethanol, ethanolamine, PEDOT: PSS (AI 4083), lead chloride (PbCl2, 99%), Lead iodide (PbI2, 99%), Methylammonium Iodide (MAI, 99.5%), and (6,6)-phenyl-C61-butyric acid methyl ester (PC61BM). Equipment included a spray-method device (Hizenith AC300-1), UV–vis–NIR Spectro-photometer (PerkinElmer), SEM (S-4800), steady-state and transient-state fluorescence spectrometer (JY Fluorolog-3-Tou), AFM (Dimension 3100), and SIMS.
4:5%), and (6,6)-phenyl-C61-butyric acid methyl ester (PC61BM). Equipment included a spray-method device (Hizenith AC300-1), UV–vis–NIR Spectro-photometer (PerkinElmer), SEM (S-4800), steady-state and transient-state fluorescence spectrometer (JY Fluorolog-3-Tou), AFM (Dimension 3100), and SIMS. Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: The Ag NWs were fabricated on PET substrates by spray method. The ZnO sol-gel precursor was prepared and deposited on the top of Ag NWs through spin-coating method. The composite electrode film was annealed on a hot plate. The MAPbIxCl3-x active layer was fabricated through one step anti-solvent method.
5:Data Analysis Methods:
The transmittance and absorption spectra were measured, and the micrograph was investigated by SEM. Photoluminescence was tested, and surface morphology was observed by AFM. The ionic migration after aging was investigated by SIMS. The J–V characteristics of devices were measured using a Keithley model 2400 source measurement unit.
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PEDOT: PSS
AI 4083
Heraeus Ltd
Hole transport layer
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(6,6)-phenyl-C61-butyric acid methyl ester
PC61BM
Sigma-Aldrich
Electron transport layer
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UV–vis–NIR Spectro-photometer
Lamada 750
PerkinElmer
Measurement of transmittance and absorption spectra
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Silver nanowires
30 nm diameter, 20–30 μm length
Naibotech
Flexible transparent electrode
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Zinc acetate
Aladdin Ltd
Precursor for sol-gel ZnO
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Dimethoxy ethanol
J&K Scientific Ltd
Solvent for ZnO precursor
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Ethanolamine
Adamas Reagent Co., Ltd
Stabilizer for ZnO precursor
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Lead chloride
PbCl2, 99%
Xi’an Polymer Light Technology Corp
Perovskite precursor
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Lead iodide
PbI2, 99%
Xi’an Polymer Light Technology Corp
Perovskite precursor
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Methylammonium Iodide
MAI, 99.5%
Xi’an Polymer Light Technology Corp
Perovskite precursor
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Scanning Electron Microscope
S-4800
Investigation of micrograph
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Steady-state and transient-state fluorescence spectrometer
JY Fluorolog-3-Tou
Photoluminescence testing
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Atomic Force Microscopy
Dimension 3100
Observation of surface morphology
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Time of Flight Secondary Ion Mass Spectrometry
SIMS
Investigation of ionic migration after aging
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Source measurement unit
Keithley model 2400
Measurement of J–V characteristics of devices
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