研究目的
To improve the nucleation and growth process for low temperature processed a-phase CsPbIBr2 film and enhance the performance of carbon based CsPbIBr2 solar cells through Zn substitution.
研究成果
Zn substitution could accelerate the nucleation process and stabilize a-phase CsPbIBr2 film under low temperature. The improve growth process could lead to a high quality CsPbIBr2 film with good crystallinity, compact surface morphology, and improved optical absorbance under low temperature annealing condition. The recombination ratio can be effectively suppressed though Zn substitution. A champion power conversion efficiency over 9% has been achieved without using HTL and metal electrode.
研究不足
The high annealing temperature and use of HTL/metal electrode would significantly increase the fabrication cost and preparation complexity. Moreover, high temperature fabrication process could impede the application on flexible device with cheap plastic substrate.
1:Experimental Design and Method Selection:
Zn substitution was used to improve the nucleation and growth process for low temperature processed a-phase CsPbIBr2 film.
2:Sample Selection and Data Sources:
CsPbIBr2 films with different Zn substitution concentrations were prepared and characterized.
3:List of Experimental Equipment and Materials:
Fluorine doped tin oxide (FTO) glass and PEN/ITO substrates, TiO2 films, CsI, PbBr2, DMSO, ZnI, commercial carbon paste.
4:Experimental Procedures and Operational Workflow:
CsPbIBr2 precursor solution was spin-coated onto TiO2-coated FTO substrate, followed by annealing and screen printing of carbon paste.
5:Data Analysis Methods:
X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), ultraviolet photoelectron spectroscopy (UPS), UV-VIS-NIR spectrophotometry, SEM, photoluminescence (PL) spectra, current density–voltage (J–V) characteristics, incident photo-to-current conversion efficiency (IPCE), electrochemical impedance spectroscopy (EIS).
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