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Transparent Conductive Materials (Materials, Synthesis, Characterization, Applications) || Graphene

DOI:10.1002/9783527804603.ch3_2 出版年份:2018 更新时间:2025-09-23 15:21:21
摘要: Graphene regards to a monolayer of carbon atoms arranged in a ?at two-dimensional (2D) honeycomb lattice. It belongs to the family of carbon nanostructures that have won two Nobel Prizes and have been the focus of intensive research and development in the past few decades with well-known members including zero-dimensional (0D) fullerenes (or bucky-balls), one-dimensional (1D) carbon nanotubes, and three-dimensional (3D) graphite as illustrated in Figure 3.2.1. Since its discovery in 2004, graphene has attracted enormous interest due to its superior physical properties including high charge carrier mobility, optical transparency, ?exibility, and chemical stability. The intrinsic graphene has a zero energy bandgap, Eg, which has prevented it to be used in a similar way to the conventional semiconductors of well-de?ned Eg. However, the low charge carrier density and high charge mobility in graphene imply that graphene can be an excellent transparent conductor (TC) with both high electrical conductivity and optical transparency. Therefore, graphene makes an excellent alternative to transparent conducting oxides (TCOs) demanded for a large variety of photonic and optoelectronic applications including ?exible displays, light-emitting devices, detectors, touch screens, transistors, electromechanical resonators, ultracapacitors, and photovoltaics (PVs).
作者: Judy Z. Wu
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Investigating the potential of graphene as a superior transparent conductor for various optoelectronic applications, including photodetectors, photovoltaics, and flexible displays, by exploring its physical properties, synthesis methods, and characterization techniques.

Graphene exhibits superior physical properties that make it a promising alternative to conventional transparent conductors for optoelectronic applications. Despite challenges in synthesis and transfer, advancements in CVD growth and doping techniques have significantly improved the performance of graphene-based transparent conductors. Future research should focus on optimizing synthesis methods and interface engineering to fully realize graphene's potential in optoelectronics.

The study acknowledges the challenges in achieving large-scale, high-quality graphene films with performance comparable to ITO, including the presence of defects and grain boundaries that reduce charge mobility and increase sheet resistance. Additionally, the transfer process of graphene from growth substrates to application substrates can introduce defects and impurities.

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