研究目的
To analyze the structural, morphological and optical properties of Cd doped ZnO and rare earth doped ZnCdO synthesized by solgel auto combustion route.
研究成果
The samples of ZnO, ZnO:Cd, ZnO:Cd+La, and ZnO:Cd+Y synthesized by sol-gel auto combustion method exhibit hexagonal wurtzite structure with changes in grain size due to doping. The optical bandgap decreases with doping, and the photoluminescence spectra show a uniform spectral response in the visible region, suggesting potential applications in optoelectronic devices.
研究不足
The study is limited to the analysis of structural, morphological, and optical properties of the synthesized samples. The potential applications in optoelectronic devices are suggested based on the observed properties but not experimentally verified.
1:Experimental Design and Method Selection:
The samples were synthesized using the solution combustion technique with glycine as fuel. The precursor solutions consisted of stoichiometric proportions of Zinc nitrate, Cadmium nitrate, Lanthanum nitrate, and Yttrium nitrate dissolved in distilled water.
2:Sample Selection and Data Sources:
The samples synthesized were ZnO, ZnO:Cd, ZnO:Cd+La, and ZnO:Cd+Y.
3:List of Experimental Equipment and Materials:
X-ray diffractometer (XRD-PAnalytical X’pert PRO CuKα), High Resolution Scanning Electron Microscope (HRSEM-FEI Quanta-200 MKII), UV-Vis-NIR spectrophotometer (Lab India UV3000+), FT-Raman Spectrometer (BrukerRFS27), Spectroflourimeter (JYFluorolog-3-11).
4:1).
Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: The aqueous solution was stirred and heated in a magnetic stirrer for 15 minutes to ensure homogeneity. The solution was then transferred to an electric mantle at 100°C, leading to a self-propagating combustion process that yielded fluffy powder samples. The powders were annealed at 900°C for 5 hours.
5:Data Analysis Methods:
The XRD patterns were analyzed for structural properties, SEM for morphological properties, UV-Vis-NIR for optical properties, and photoluminescence spectra for emission properties.
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