研究目的
To develop a new synthesis approach for ordered mesoporous carbon (OMC) coatings with preformed Pt nanoparticles to enhance the performance of the hydrogen evolution reaction (HER) in acidic environments by maximizing the utilization of platinum.
研究成果
The incorporation of preformed colloidal Pt nanoparticles into OMC films presents a promising approach to enhance the HER performance by maximizing Pt utilization and avoiding pore blocking by binders. The PtNP/OMC films showed superior performance compared to traditional Pt/C catalysts, especially at high current densities.
研究不足
The study focuses on the synthesis and initial performance testing of PtNP/OMC films. Long-term stability under operational conditions and scalability of the synthesis method are areas for further investigation.
1:Experimental Design and Method Selection:
The synthesis involves the incorporation of preformed colloidal Pt nanoparticles into the synthesis of OMC films. The method avoids the use of Na?on binder, which typically blocks pores and active sites.
2:Sample Selection and Data Sources:
Colloidal Pt nanoparticles were synthesized and characterized before incorporation into the OMC films. The films were then tested for HER performance.
3:List of Experimental Equipment and Materials:
Equipment includes SEM, TEM, XRD, and electrochemical testing setups. Materials include PtCl2, resorcinol, formaldehyde, Pluronic F127, and THF.
4:Experimental Procedures and Operational Workflow:
The synthesis involves mixing preformed Pt nanoparticles with a polymer resin, casting the mixture into films, and subsequent thermal treatments to form the OMC structure.
5:Data Analysis Methods:
Performance in HER was evaluated through cyclic voltammetry and chronopotentiometry. Particle size and distribution were analyzed via TEM and XRD.
独家科研数据包,助您复现前沿成果,加速创新突破
获取完整内容-
Pluronic F127
Sigma-Aldrich
Structure-directing agent in the synthesis of ordered mesoporous carbon films.
-
PtCl2
Alfa Aesar
Precursor for the synthesis of colloidal Pt nanoparticles.
-
Tetraoctylammonium bromide
Sigma Aldrich
Used in the synthesis of the reducing agent for colloidal Pt nanoparticles.
-
Potassium triethylborohydride
Sigma Aldrich
Used in the synthesis of the reducing agent for colloidal Pt nanoparticles.
-
Resorcinol
Sigma-Aldrich
Carbon precursor in the synthesis of ordered mesoporous carbon films.
-
Formaldehyde
Sigma-Aldrich
Carbon precursor in the synthesis of ordered mesoporous carbon films.
-
Na?on solution
Sigma-Aldrich
Used in the preparation of reference catalyst films for comparison.
-
Pt on Vulcan
XC 72R
BASF
Reference catalyst for comparison in HER performance testing.
-
登录查看剩余6件设备及参数对照表
查看全部