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Low dimensional metal halide perovskites and hybrids

DOI:10.1016/j.mser.2018.12.001 期刊:Materials Science and Engineering: R: Reports 出版年份:2019 更新时间:2025-09-23 15:19:57
摘要: Organic-inorganic metal halide hybrids are an important class of crystalline materials with exceptional structural and property tunability. Recently metal halide perovskites with ABX3 structure have been extensively investigated as new generation semiconductors for various optoelectronic devices, including photovoltaic cells, light emitting diodes, photodetectors, and lasers, for their exceptional optical and electronic properties. By controlling the morphological dimensionality, low dimensional metal halide perovskites, including 2D perovskite nanoplatelets, 1D perovskite nanowires, and 0D perovskite quantum dots, have been developed to exhibit distinct properties from their bulk counterparts, due to quantum size effects. Besides ABX3 perovskites, organic-inorganic metal halide hybrids, containing the same fundamental building block of metal halide octahedra (BX6), can also be assembled to possess other types of crystallographic structures. Using appropriate organic and inorganic components, low dimensional organic-inorganic metal halide hybrids with 2D, quasi-2D, corrugated-2D, 1D, and 0D structures at the molecular level have been developed and studied. Due to the strong quantum confinement and site isolation, these low dimensional metal halide hybrids at the molecular level exhibit remarkable and unique properties that are significantly different from those of ABX3 perovskites. In light of the rapid development of low dimensional metal halide perovskites and hybrids, it is indeed timely to review the recent progress in these areas. Also, there is a need to clarify the difference between morphological low dimensional metal halide perovskites and molecular level low dimensional metal halide hybrids, as currently the terminologies of low dimensional perovskites are not appropriately used in many cases. In this review article, we discuss the synthesis, characterization, application, and computational studies of low dimensional metal halide perovskites and hybrids.
作者: Chenkun Zhou,Haoran Lin,Qingquan He,Liangjin Xu,Michael Worku,Maya Chaaban,Sujin Lee,Xiaoqin Shi,Mao-Hua Du,Biwu Ma
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To review the recent progress in the synthesis, characterization, application, and computational studies of low dimensional metal halide perovskites and hybrids, and to clarify the difference between morphological low dimensional metal halide perovskites and molecular level low dimensional metal halide hybrids.

The review highlights the unique properties and applications of low dimensional metal halide perovskites and hybrids, emphasizing the need for clear terminology to distinguish between morphological and molecular level low dimensional materials. It also points out the potential for future research in this field.

The paper does not discuss specific technical and application constraints of the experiments or potential areas for optimization in detail.

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