研究目的
To investigate the photoluminescence and temperature sensing properties of Ho3+/Yb3+ codoped (Y0.88La0.09Zr0.03)2O3 transparent ceramics, focusing on their potential for optical thermometry with high sensitivity and immunity to excitation power variations.
研究成果
The Ho3+/Yb3+ codoped transparent ceramics exhibit excellent photoluminescence, high transparency, and power-insensitive temperature sensing with a maximal sensitivity of 71.28×10?4 K?1 at 563 K, making them promising for sensors, displays, and lasers.
研究不足
The study is limited to specific doping concentrations and temperature ranges (up to 563 K); potential limitations include the scalability of the synthesis method and the need for further testing in practical applications.
1:Experimental Design and Method Selection:
The study uses a high-temperature solid-state reaction method to prepare transparent ceramics, with characterization techniques including XRD, SEM, UV-Vis spectrophotometry, and luminescence spectroscopy to analyze structural, optical, and thermal properties. The fluorescence intensity ratio (FIR) technique is employed for temperature sensing.
2:Sample Selection and Data Sources:
Samples are (YbxHo0.01Y0.87-xLa0.09Zr0.03)2O3 with x=0.03, 0.05, 0.08, and 0.10, prepared from high-purity oxide powders.
3:01Y87-xLa09Zr03)2O3 with x=03, 05, 08, and 10, prepared from high-purity oxide powders. List of Experimental Equipment and Materials:
3. List of Experimental Equipment and Materials: Equipment includes an X-ray diffractometer with Cu Kα1 radiation, SEM (SU8010 model), SHIMADZU UV-3600 UV-Vis spectrophotometer, spectrometer (HORIBA JOBIN-YVON Fluorolog-3) with 980 nm laser diode, and a heating device (TAP-02 temperature controlling system). Materials are Yb2O3, Ho2O3, Y2O3, ZrO2, and La2O3 powders (99.99% purity).
4:99% purity). Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: Powders are mixed, ground, calcined at 1100°C, pressed into pellets, and sintered at 1700°C. Characterization involves XRD for phase analysis, SEM for microstructure, transmittance measurements, and luminescence spectra recording under 980 nm excitation. Temperature-dependent measurements are done from 293 K to 563 K.
5:Data Analysis Methods:
Data is analyzed using fitting functions for FIR (e.g., FIR = A * exp(-B/T) + C * exp(-D/T)) and sensitivity calculations (Sa = dFIR/dT).
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UV-Vis spectrophotometer
UV-3600
SHIMADZU
Analyze transmittance of ceramic samples
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X-ray diffractometer
Cu Kα1 radiation
Measure crystal structure of sintered ceramics
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SEM
SU8010
Microstructure observations of ceramics
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Spectrometer
Fluorolog-3
HORIBA JOBIN-YVON
Record UC and near-infrared luminescence spectra
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Laser diode
980 nm
Excitation source for luminescence measurements
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Heating device
TAP-02 temperature controlling system
Control temperature for dependent measurements
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Thermocouple
Monitor experimental temperature
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