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Highly efficient method for oxidation of dissolved hydrogen sulfide in water, utilizing a combination of UVC light and dissolved oxygen

DOI:10.1016/j.jphotochem.2018.12.005 期刊:Journal of Photochemistry and Photobiology A: Chemistry 出版年份:2019 更新时间:2025-09-23 15:23:52
摘要: Hydrogen sul?de is a hazardous contaminant that may appear in well-water and in sewage streams. Here we present a very e?cient way for the removal of H2S from well-water, based on combining UVC light and oxygen. The method was tested with H2S-enriched tap water as well as with natural well water, both of which containing up to 20 mg/L of H2S. A conversion of up to 90% was obtained within a residence time of no more than a few minutes. The quantum e?ciency, de?ned as the ratio between the number of removed H2S molecules to the number of impinging photons, was found to be as high as 70%, depending on conditions. The main product was found to be sulfate, without the appearance of elemental sulfur, i.e. with no major change in turbidity. The absence of sulfur in the outlet stream in of large importance when treating H2S-containing well-water, since it omits the need for posttreatment removal of particles. Results are explained by the excitation of HS- species, following by formation of polysul?de anions that readily react with any formed elemental sulfur, eventually yielding sulfate ions.
作者: Yizhak Tzvi,Yaron Paz
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Investigating the e?cient removal of hydrogen sul?de from water using a combination of UVC light and dissolved oxygen, focusing on complete oxidation to sulfate without producing elemental sulfur.

The combination of UVC light and oxygen is highly effective for oxidizing hydrogen sul?de to sulfate in water, achieving up to 90% conversion in minutes with quantum efficiencies up to 70%. This method avoids the formation of elemental sulfur, eliminating the need for post-treatment filtration. The mechanism involves light absorption by HS- ions, leading to polysul?de formation and complete oxidation. This approach offers a chemical-free, efficient alternative for H2S removal in well-water treatment, with potential applications in improving water quality for agriculture and other uses.

The process requires transparent water for effective light penetration; high turbidity or colored water may reduce efficiency. Oxygen concentration must be sufficient, especially for high H2S levels, necessitating bubbling in low-oxygen water. pH affects reaction rate, with optimal performance around neutral to basic conditions. The method may not be cost-effective for very large-scale applications without further optimization of light sources and oxygen supply.

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