研究目的
To develop a compact high-voltage/frequency variable driving circuit for dispersed-type inorganic electroluminescent devices and investigate the effects of preparation conditions on their electrical and emission properties.
研究成果
A compact voltage/frequency variable circuit was successfully designed, enabling control of voltage (up to 140 Vpp) and frequency (270 Hz to 2.4 kHz) for driving dispersed-type inorganic EL devices. Emission properties are strongly influenced by frequency and preparation conditions, such as device structures and material dispersion. Defects and current paths impact uniformity and efficiency, but the integration of fluorescent dyes allows for color variation. Future work could focus on optimizing materials and circuits for higher performance.
研究不足
The EL devices suffer from low luminance and efficacy, non-uniform emission due to defects in flexible substrates, and limited color choice. The driving circuit has voltage and frequency constraints (up to 140 Vpp and 2.4 kHz), and there are issues with leakage currents and defects affecting performance.
1:Experimental Design and Method Selection:
The study involved designing a frequency-variable high-voltage oscillation circuit with three modules (boosting, frequency conversion, voltage conversion) and preparing dispersed-type inorganic EL devices with variations in layers and materials. Theoretical models for circuit oscillation and impedance were used.
2:Sample Selection and Data Sources:
Four types of EL cells were prepared using ITO glass or ITO/PET film as transparent electrodes, ZnS:Cu,Cl phosphor inks, BaTiO3 dielectric inks, and Ag/C back electrode inks, purchased from ImageTech Inc. and Geomatec Co., Ltd.
3:List of Experimental Equipment and Materials:
Equipment includes a chemical impedance analyzer (IM3590, Hioki EE Co.), plasma process monitor (C7460, Hamamatsu Photonics K.K.), UV-vis spectrophotometer (V-670, Jasco Co.), transformer (HP-068, Toyomizu Dengenkiki Co. Ltd.), variable resistors, CMOS logic IC (TC 4069), MOSFET (2SK 3234), three-terminal regulator (LM 317), and various capacitors and resistors.
4:Experimental Procedures and Operational Workflow:
EL devices were fabricated by coating layers (phosphor, dielectric, back electrode) using a hand coater, drying at 90°C for 20 minutes. The driving circuit was assembled and used to apply voltages (up to 140 Vpp) and frequencies (270 Hz to 2.4 kHz) to the EL cells. Impedance, emission spectra, and absorption spectra were measured.
5:4 kHz) to the EL cells. Impedance, emission spectra, and absorption spectra were measured. Data Analysis Methods:
5. Data Analysis Methods: Data were analyzed using theoretical equations for circuit oscillation and impedance, and spectral data were interpreted based on literature comparisons.
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plasma process monitor
C7460
Hamamatsu Photonics K.K.
Measuring luminescence of EL cells
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UV-vis spectrophotometer
V-670
Jasco Co.
Measuring absorption spectra of phosphors
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chemical impedance analyzer
IM3590
Hioki EE Co.
Measuring impedance of EL cells over a frequency range
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transformer
HP-068
Toyomizu Dengenkiki Co. Ltd.
Boosting voltage in the driving circuit
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CMOS logic IC
TC 4069
Used in the RC oscillator circuit for frequency conversion
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MOSFET
2SK 3234
Switching in the driving circuit
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three-terminal regulator
LM 317
Voltage regulation in the driving circuit
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variable resistor
Adjusting frequency and voltage in the circuit
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ITO glass
Geomatec Co., Ltd.
Transparent electrode in EL devices
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ZnS:Cu,Cl phosphor ink
ImageTech Inc.
Phosphor layer in EL devices
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BaTiO3 dielectric ink
ImageTech Inc.
Dielectric layer in EL devices
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Ag/C ink
ImageTech Inc.
Back electrode in EL devices
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ITO/PET film
ImageTech Inc.
Flexible transparent electrode in EL devices
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red fluorescent dye
rhodamine B
Added to phosphor for color variation
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